Data:Nitration of methyl benzoate:Weight of filler paper: 0.682gMp product: 76-77 CNitration of Acetanilide:Weight of filler paper: 0.691gWeight of filler paper product: 1.232gMp product: 212-214 Ccalculate the theoretical yield for the mononitration of (a) acetanilide and (b) methyl benzoate Reagents and Propertiesafnimolar masssubstancequantity(g/mol)d (g/mL)mp (C) bp ("C)acetanilide0.5 g5-10 mL135.17113-115ethanol, 95%methyl benzoatemethylnitrobenzoate*46.07780.55 g136.151.094-12198181.13DowA dosbood amutnitroacetanilide*180.16nitric acid conc.0.5 mL63.01sulfuric acid conc. 1.6 mL98.08"productod i odt "bi

The question involves calculation of theoretical yield of the nitrated product. by considering the…

Nitration of methyl benzoate: Weight of filler paper: 0.682g Mp product: 76-77 C Nitration of Acetanilide: Weight of filler paper: 0.691g Weight of filler paper product: 1.232g Mp product: 212-214 C calculate the theoretical yield for the mononitration of (a) acetanilide

Nitration of methyl benzoate: Weight of filler paper: 0.682g Mp product: 76-77 C Nitration of Acetanilide: Weight of filler paper: 0.691g Weight of filler paper product: 1.232g Mp product: 212-214 C calculate the theoretical yield for the mononitration of (a) acetanilide

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter5: Distillation

Section: Chapter Questions

Problem 11Q

See similar textbooks

Related questions

Q: According to Table 23-1, the nitration of phenol results in a product mixture that is 50% ortho and…

A: The C-H bond weaker than the C-D bond due to this the elimination of D from the sigma complex is…

Q: Furan undergoes electrophilic aromatic substitution more readily than benzene; mild reagents and…

A: Furan undergoes bromination more easily when compared to benzene because of the more reactive…

Q: Reduction of Vanilin What is the limiting reagent in this reaction? Is it ok to use Lithium…

A: 1.1 mole NaBH4 contains 4 reactionable hydrogen.Molar ration of vaniline:NaBH4 =4:1.1mole NaBH4…

Q: Which cannot be prepared in high yield treatment of a ketone or a diketone with a slight excess of…

A: LDA abstracts proton from the alpha position to the carbonyl group of ketone. The negative charged…

Q: Calculate the theoretical yield and percent yield. Reaction between 2.0g…

Q: 8 Organocuprates predominantly react to give 1,4-addition products with a,B-unsatu- rated carbonyl…

A: The detailed mechanism with stereochemistry is given below :

Q: Provide the reagent sequence for the following reactio O 1) NaNH2, 2) MeCl, 3) NaNH2, 4) EtCI O 1)…

A: Correct answer is (1) NaNH2 , (2) MeCl , (3) NaNH2 , (4) EtCl , (5) Na, NH3

Q: Sketch and explain the IR, UV, mass, and NMR (1H and 13C) spectroscopy data of Benzonitrile

A: There are different types of spectroscopic techniques for the identification and characterisation of…

Q: The photochemical axidation of pentane (CH,CH,CH,CH,CH,) by hydroxyl radical yields the formation of…

A: The photochemical oxidation of hydrocarbons in air with hydroxyl radicals initiates a reaction…

Q: . discuss the reaction of ethanal in schiff'test. briefly explain.

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: What is the limiting reagent in the synthesis of triphenylmethanol via Grignard reagent? Show the…

A: The limiting reagent in a reaction is a reactant that is completely consumed during the course of…

Q: Data Sheet Electrophilic Aromatic Substituhon - NitratioN acetanilide methyl benzoate amount of…

A: Nitration is a process of introduction of the NO2 group. The reagent used is called initiating…

Q: Preparation of para-iodonitrobenzene 1. Weight of p-nitroaniline = 0.552 g 2. Weight of…

A: Please find the attached sheet.

Q: Ar-N2 BF4 OH 4а-d Ar NABF4 catalyst MEOH solvent Bre BF4 rt, 6 h 57% rt За 3b 1а-d

A: Introduction: Given reaction is Suzuki Cross-Coupling reaction and we have to provide its detailed…

Q: Compare the reactivity of following compounds for coupling reactions Phenol, p-nitro aniline,…

A: An azo coupling reaction involves reaction between a diazonium compound and any other aromatic…

Q: hat is the purpose of adding CaCO3 or NaHCO3 in the Mohr Method determination of chloride? Than

A: the answer is as follows:

Q: Acetoxybenzene (PhOC(=O)OCH3) is much less reactive than ethoxybenzene (PhOCH2CH3) in electrophilic…

Q: What is the percentage yield for experiment step 1 and step 2: Preparation of…

Q: The question has been attached as a picture. Please answer this question as every other question I…

A: Please note that ethyloxirane mentioned in the question has a structureSo the name in the brackets…

Q: The NMR spectrum of 3-nitroaniline was taken in deuterated dimethylsulfoxide (DMSO), not CDCl3. Why?…

A: In the NMR spectrum there is a transfer of acidic proton from the solute to the deuterated solvent…

Q: drug synthesis from Sandmeyer reaction

A: Sandmeyer reaction : It is a aromatic nucleophilic substitution which occurs through radical…

Q: Two Sonogashira coupling reactions can be used to make unsymmetrical diaryl alkynes by first using…

A: The sequence of reactions starting with trimethylsilylacetylene involves reacting the…

Q: Outline all steps (not mechanism) in a possible laboratory synthesis of each of the following…

A: In this question, we want to Synthesized these two given Compound from Toluene. How we can…

Q: Calculate the theoretical yield of virstatin ethyl ester and virstatin.

A: Theoretical yield is the maximum amount of product can be generated from the given amount of…

Q: Giving an example for each describe the following reactions :(i) Hofmann’s bromamide reaction(ii)…

A: To study the naming reaction

Q: how to find yield percent for Synthesis of cis- and trans-dichlorobis(ethylenediamine)cobalt (III)…

A: Given, Initially, Cobalt (ll) = 0.3015 g and chloride hexahydrate = 0.2503 g Obtained, trans product…

Q: Provide the full reaction mechanism for the preparation of Aspirin (Not salicylate) starting from a…

Q: Complete the table by drawing the sulfonamides produced, if any, upon the addition of BSC and excess…

A: ✓About to BSC- Benzene sulphonyl chloride is abbreviated as BSC.It is a chemical reagent called…

Q: What is the purpose for all of the following ? Carry out an electrophilic aromatic substitution…

A: Electrophilic aromatic substitution reaction are the subdtitution reaction in which an electrophilic…

Q: is this a one to one reaction? what does the chemical equation look like? Preparation of Acetanilide…

A: one to one reaction is that when from one reactant, one product is formed.

Q: ive a detailed mechanism including all resonance isomers for intermediates (show electron flow) for…

A: Given Reactant 1-t-butyl-2,5-dimethoxybenzene. Product 1,4-di-t-Butyl-2,5-dimethoxybenzene Reaction…

Q: What does a theoretical yield of 0.0488g and a percentage error of 3.6% mean in a Grignard synthesis…

A: Given: A theoretical yield of 0.0488 g and a percentage error of 3.6%.

Q: Give the reason(s) of the following statements: 1. t-Butyl > isopropyl > ethyl > methyl for relative…

A: Hello. Since your question has multiple sub-parts, we will solve the first three sub-parts for you.…

Q: In an aqueous solution containing sodium bicarbonate, aniline reacts quickly with bromine to give…

A: Nitration of aniline happens in the presence of nitration mixture (concentrated nitric acid and…

Q: Electrophilic bromination of an equimolar mixture of methylbenzene (toluene) and…

A: Methyl group is Ortho para director due it's inductive and hyperconjugation effects.

Q: Write a mechanism for the nucleophilic aromatic substitution reaction of 2,4-dinitrobromobenzene…

A: SCN- nucleophile attacks on Carbon which C-Br bond and π bond transfer towards NO2 and then again…

Q: subtitution is determined by the substituent which has a higher activation effect F, Cl, Br, and…

A: Statement 1 and statement 3 are false 1 Electron-withdrawing groups (EWGs) passivates the…

Q: Reaction of hydrazine,KOH,triethylene glycol (Wolf-Kishner conditions) with CH3CH₂C(O)C6H5 forms O…

A: Wolf-Kishner reduction of ketones yields a saturated hydrocarbon.

Q: The reaction between Pl3, PSCl3 and Zn powder gives P3ls as one of the products. The sołution state…

A: This Question is based upon P31 NMR.

Q: (a)Calculate theoretical yield of both williamson ether synthesis of phenacetine and amide synthesis…

A: Percent yield: It is % of product obtained on basis of theoretical and experimental aspects. It is…

Q: FRIEDEL-CRAFTS ALKYLATION The laboratory manual procedure was followed using the following…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: Give balanced overall reaction.

A: Important points. Friedal crafts alkylation is an electrophilic substitution reaction which…

Q: Provide all resonance structures of the sigma complex when aniline reacts with an electrophile to…

A: Reaction is taking place between aniline and Br2 (Br electrophile)

Q: Although nitration of aniline is slow and gives mostly meta substitution, nitration of acetanilide…

Question

Data:

Nitration of methyl benzoate:

Weight of filler paper: 0.682g

Mp product: 76-77 C

Nitration of Acetanilide:

Weight of filler paper: 0.691g

Weight of filler paper product: 1.232g

Mp product: 212-214 C

calculate the theoretical yield for the mononitration of (a) acetanilide and (b) methyl benzoate

Reagents and Properties
afni
molar mass
substance
quantity
(g/mol)
d (g/mL)
mp (C) bp ("C)
acetanilide
0.5 g
5-10 mL
135.17
113-115
ethanol, 95%
methyl benzoate
methyl
nitrobenzoate*
46.07
78
0.55 g
136.15
1.094
-12
198
181.13
DowA dos
bood amut
nitroacetanilide*
180.16
nitric acid conc.
0.5 mL
63.01
sulfuric acid conc. 1.6 mL
98.08
"product
od i odt "bi

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

chools.schoology.com/common-assessment-delivery/start/4573067641?action%3Donresume&submissionld%3547892539 150 140 130 120 110 100 NANO 90 80 70 60 NH C Ka Náci 50 40 30 20 KCIÓ, 10 Cez(so 10 20 30 40 50 60 70 80 90 100 Temperature (C) The compound with the least solubility at 50 °C is OKI O NANO3 O KNO3 O NH3 O NH&CI O KCI O NaCI O KCIO3 O Cex(SOa)a DELL & Grams of solute
Unknown Mixture #1 Unknown Mixture #2 Sample caffeine ibuprofen aspirin acetaminoph en Distance to solvent front 14,70 cm 14,70cm 14.70cm1u.70 cm 1나,구 cm |14.구0cm 5. 70 cm 11.90 cm I.85cm Distance Spot(s) traveled 175 cm 13.75cm 11.9 5 cm 6.4 0 cm 13,75 cm 13.75 cm 38 78 1908 .8095 Calculated R:(s) 119 ,9354 812 9 43 S .9354 9354 #1:Aspirin an d lbuprofen Components of Unknowns #2: Ace taminophen, aspirin an d ibu profen D. Additional Exercises 1. Which of the substances tested is most polar? What parts of the structure of this substance is polar? The Sul 2. Which of the substance tested is most non-polar? What parts of the structure of this substance in non-polar?
Cou X A Ch 6 x C Sear X * Sear X Sear x b > Hov x2 Con x Con X b Sear X y! cher X M Inbc X M Inbc X + Vent X 8 https://www.saplinglearning.com/ibiscms/mod/flcn/view.php?id3D15033867 + Sapling Learning macmillan learning Ch 6 Homework Jason Bauer , Sapling Learning > Ventura College - Chem V30 (31510) - Spring21 - ALAWDI > Activities and Due Dates > Ch 6 Homework E 20 of 24 Questions O Assignment Score: O Resources O Hint 68.3% Check Answer O 16 Question 100% x2 Question 20 of 24 > 1 of 5 Attempts Correct How many moles of CaCl2 are in 7.76 x 1024 formula units? O 17 Question 100% x2 1 of 5 Attempts Correct 7.76 x 1024 formula units = mol O 18 Question 100% x2 2 of 5 Attempts Correct O 19 Question 1 of 5 Attempts 100% x2 Correct 20 Question 0% O of 5 Attempts 21 Question 0% x2 O of 5 Attempts © 2011-2021 Sapling Learning, Inc. about us careers privacy policy terms of use contact us help 1:42 PM P Type here to search 99+ 2/18/2021 19
ks.com/alekscgi/x/Isl.exe/1o_u-IgNslkr7j8P3jH-IQUHIQg6bJxmeSyVpHOEB1plef9xyC5Ca9Q15ULF571w. A to ©T GI O STATES OF MATTER Finding mass or volume from percent concentration 0/5 Ma Lidocaine, a widely used local anesthetic, is available as a 0.50 %(w/v) solution for injection. Calculate the volume of this solution that contains 90. mg of lidocaine. Be sure your answer has a unit Symbol and is rounded to the correct number of significant digits. X10 Explanation Check O 2022 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Center Accessibility Insert Delete F12 PriScr F10 F11 F9
(c) 1. THF H2C CEN 7. 2. H30* N(CH312 (d) 1. THF N' 2. H3O* 2016 Cmn Laung
LEKS & Beyondtabz- General x A ALEKS - Christian Rodriguez H x www-awu.aleks.com/alekscgi/x/islexe/1o u-lgNsikr7j8P3jH-UIKKWbITryejiakVnFaC1BKPUCOANhTCgXBGB yaRn-VHgAGTVkypitEfk1SK 每☆ Homework 4- Chapter 12 Thermodynamics Question 1 of 20 (2 points) Question Attempt1 of Unlimited 3 10 11 12 The heat of fusion AH, of ammonia (NH,) is 5.6 kJ/mol. Calculate the change in entropy AS when 460. g of ammonia freezes at -78.0 C. Be sure your answer contains a unit symbol and the correct number of significant digits. Save For Later Submit Check 02021 MeGwHEducatian A Rgho Reserved m af Ue P Escribe aqui para buscar
Hexanoic acid was added to an immiscible biphasic solvent sysem, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D1) of hexanoic acid in CCl4 with respect to water.
(i) (ii) (iii) (iv) 'I OMe HO H g H N Me Br SnMe3 OSiMe3 CHO OH NaNH, NH3 (1) Phl, Pd(PPH3)4 THF, reflux 1. Ph3P=CMe2 2. "Bu4NF 3. H30 + CH₂12, Zn C C₂H₂NO D C₁1H₁1N E C10H16O F C15H26O2
Weight of crude acetanilide = 2.2 grams Weight of pure acetanilide = 1.5 grams Melting point of recrystallized acetanilide = 114.3 C (a) What is the % yield? (b) What is the % purity?
n eFundi : NCHE 121 1- NCHE 121 - Test 8 - Ve X G c8h12i iupac name - C X b My Questions | bartleb x R° (PDF) The Fourth Indu: X R° (PDF) In dis tree - 4 W x A docs.google.com/forms/d/e/1FAlpQLScN5aWTObzfQAgIF5ETgigA7N4LhreJo3ILGJ6Zwl0D7iboNQ/formResponse Question 3: Which of the following intermolecular forces would you expect between the haloalkane molecules in Figure 3? * Hydrogen bonds Dipole-dipole forces Dipole-induced dipole forces Induced dipole-induced dipole forces Figure 3 17:30 P Type here to search 38°C Partly sunny 2021/11/04
C B) C) D) E) (C6H5)3P NH₂ Zn(Hg) HCI ۵۰۰ NaOH heat DMSO 1. Excess CH31 2. Ag₂O, H₂O 3. heat -O 53% 35°F Cloudy 12
It was found that solubility of benzoic acid in water at differont temjperatures Was aceording to the follewing tuble. Tc 6 0 40 30 Logs 1.20 Jimol 1.415 1.58 1.77 calculate tne Valux of the chanye in enthalpy graphically?