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Chemistry: An Atoms First Approach

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter4: Molecular Structure And Orbitals

Section: Chapter Questions

Problem 13Q

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Match the indicated atoms (red) to the proper hybridization state.
1
11
111
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2
H
IV
H-C-H
11
H-C=N:
III
III
I
111
sp
sp
sp²
sp
IV
ci;
X
X
X

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Molecule or Polyatomic HOCI NO₂ N₂H4 H₂O₂ Hint: the oxygens are connected (CH3)2NH Lewis structure H¬O—CI: | : 0=N–6: H-N-N-H H H H-0-0-H H H H-C-N -C-H .. HHH Hybrid- ization AXE 3 sp AX₂E2 2 sp² AX₂E 3 sp³ AX3E 3 sp AX₂E2 3 AX3E Electron pair geometry Molecular shape tetrahedral bent trigonal planar bent tetrahedral trigonal pyramidal tetrahedral bent tetrahedral trigonal pyramidal Bond angles ~109.5° ~109.5° all ~109.5° all ~109.5° all ~109.5° Bond Polarity Molecular Polarity if the molecule is polar, add a dipole arrow if not polar, state so and why H H H²O-OH Н H H" H H H Н Cl H 'H H
3. Predict (a) the approximate bond angle, (b) the hybridization around the indicated atoms (the atoms to which the arrows are drawn in the structures below). Write your answers near the corresponding labels (1 to 5) in the drawings. (Note: the lone pairs on the F atoms are omitted for clarity.) H. 1 F 2 4 F Br -F С -о-н F F 'N : 1: 2: 3: 4: 5:
ar moiecuie 2. CHCI, Steric Number= 3-D Sketch (use wedges and dashes as appropriate) BALPA= :ci-c-CI: Bond angle(s) | Shape = Hybridization #o bonds = #n bonds = Y Polar molecule? Circle one:
Molecule or Polyatomic BrF5 2- SiO3² NH4CIO₂ K3PO4 Lewis structure 3 K+ F Br. H H-N-H H .. ܀ :O: F o=d-0: : 0: + :O: 2- 3- Hybrid- ization AXE sp³d² AX-E 2 sp² AX3 3 sp AX4 sp AX₂E₂ sp³ AX4 Electron pair geometry Molecular shape octahedral square pyramidal trigonal planar trigonal planar tetrahedral tetrahedral tetrahedral bent tetrahedral tetrahedral Bond angles (eq) 90° (ax) 90° all 120° all ~109.5° all ~109.5° Bond Polarity Molecular Polarity if the molecule is polar, add a dipole arrow if not polar, state so and why H H T S F H OP F ciso
1. Calculate the formal charge on the labeled atoms (bold-faced). Predict hybridization of those atoms as well. All non-bonding electrons are shown. 4-3= 1+ Spå ÇH3 H3C CH3 3-4=E1 sp3 F BF 6-5 = 1+ :OH spa H3C CH3
4) Which set of hybridization for the indicated atoms in the structure below is CORRECT? CH3 A) B) C) D) CH₂ 1 =N- || IV | = sp³; || = sp³; III = sp² and IV = sp³. I= sp³; || = sp²; III = sp and IV = sp. | = sp³; || = sp²; III = sp² and IV = sp². | = sp²; || = sp³; III = sp and IV = sp³.
Complete the following table by providing theVSEPR-name and hybridisation (sp, sp2 or sp3) ofthe atom indicated by the arrow.
Q3. Draw Lewis structure, indicate formal charge on each atom, determine the hybridization of all interior atoms, show the and sketch the orbital overlapping structure. a) N₂H₂ b) N₂H4 c) HCN d) CCl4 Q4. Draw the molecular diagra on whether the molecule can exit or not. a) F₂-² b) Liz-² c) Be₂¹² d) (₂*² CONFI ISTANBU ENERAL C GNMENT iven compounds and predict the bond order AL, DO NOT PY POL UNIVERSITY CRY
harks People Tab Window Help nd Tap Cengage Learning Use The Molecular OrbitalEne: X + evo/index.html?deploymentld%3D55750828934189288909969212&elSBN=97813056... INDTAP Use the References to access important values if needed for this question. What atomic or hybrid orbitals make up the T bond between C, and C, in propyne, CHCCH3? (C, is the first carbon in the formula as written.) orbital on C+ orbital on C2 How many o bonds does C, have in CHCCH3? How many TI bonds does C, have?
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Answer the questions below about the highlighted atom in this Lewis structure: H :0: | .. Н— С C 0 – H - | H In how many sigma bonds does the highlighted atom participate? In how many pi bonds does the highlighted atom participate? What is the orbital hybridization of the highlighted atom?
"Isl.exe/1o_u-lgNslkr7j8P3jH-IB-3LP6uMdqS-27IPNKKRZON-Bs3\- O STRUCTURE AND PROPERTY RELATIONSHIPS Using hybridization to predict relative length and strength of. Examine the labeled bonds in the structures below and determine the relative strength and length for each row. Structure Which bond is weaker? Which bond is shorter? (Choose one) (Choose one) Cl (Choose one) (Choose one) (Choose one) (Choose one) H.

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