A chemical engineer is studying the following reaction: CH4(9)+2H₂S(g) → CS₂(g) + 4H₂(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 1.9 × 10². The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B с compound CHA H₂S CS₂ H₂ CH₂ H₂S CS₂ H₂ CH4 H₂S CS₂ H₂ pressure 7.83 atm. 1.22 atm 3.61 atm 7.65 atm 8.15 atm 1.87 atm 3.29 atm 6.36 atm 8.47 atm 2.52 atm 2.97 atm 5.07 atm expected change in pressure Ot increase Ot increase Ot increase O 1 increase Ot increase ↑ Ot increase O † increase Ot increase Ot increase Ot increase Ot increase 1 increase O decrease ↓ O decrease O decrease O decrease O decrease ↓ O decrease O decrease O decrease O decrease O decrease O↓ decrease O↓ decrease O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) O (no change)

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Chapter12: Chemical Equilibrium
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Using an equilibrium constant to predict the direction of spontaneous...
A chemical engineer is studying the following reaction:
CH₂(g)+2H₂S(g) → CS₂(g)+4H₂(g)
At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.9 × 10².
The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. She then measures the composition of the
mixture inside each vessel from time to time. Her first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time she measures the compositions.
reaction
vessel
A
B
U
compound
CHA
4
H₂S
CS2
H₂
CHA
H₂S
CS₂
H₂
CH_
H₂S
CS₂
H₂
pressure
7.83 atm
1.22 atm
3.61 atm
7.65 atm
8.15 atm
1.87 atm
3.29 atm
6.36 atm
8.47 atm
2.52 atm
2.97 atm
5.07 atm
expected change in pressure
increase
↑ increase
↑ increase
↑ increase
increase
↑ increase O decrease
increase
↑ increase
increase
↑ increase
↑ increase
decrease
↑ increase
↓ decrease
decrease
↓ decrease
↓ decrease
decrease
decrease
↓ decrease
decrease
O decrease
decrease
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
Transcribed Image Text:Using an equilibrium constant to predict the direction of spontaneous... A chemical engineer is studying the following reaction: CH₂(g)+2H₂S(g) → CS₂(g)+4H₂(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.9 × 10². The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B U compound CHA 4 H₂S CS2 H₂ CHA H₂S CS₂ H₂ CH_ H₂S CS₂ H₂ pressure 7.83 atm 1.22 atm 3.61 atm 7.65 atm 8.15 atm 1.87 atm 3.29 atm 6.36 atm 8.47 atm 2.52 atm 2.97 atm 5.07 atm expected change in pressure increase ↑ increase ↑ increase ↑ increase increase ↑ increase O decrease increase ↑ increase increase ↑ increase ↑ increase decrease ↑ increase ↓ decrease decrease ↓ decrease ↓ decrease decrease decrease ↓ decrease decrease O decrease decrease (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change)
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