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- 3. Complete the following intramolecular dehydration reactions for alcohols. Draw the structure of the product. Name the reactant and the product. a) Cy-C-CH-oH 18UC b) CHy CH-Cy-CHy 180C OH c) 180c 4. Complete the following intermolecular dehydration reactions for alcohols. Draw the structure of the product. Name the reactant and the product. a) CHy-CH-OH b) Ho SわふわSわ 5. Complete the following oxidation reactions for alcohols. Draw the structure of the product. Name the reactant and identify the type of compound formed in the product. a) hpWrite the complete equation for the dehydration reaction of the following alcohols. If more than one product can be formed, and one of the products is the major product, clearly indicate which one is the major product. If no dehydration reaction can occur, you must clearly indicate this by writing "no reaction" CH,CH, OH a. b. CH, CHCH, CH CH,CH, CH, OHDrinking of too much alcohol cause liver cirrhosis because ethanol is converted to toxic * Acetone Ethanal Acetic acid Methyl ethanoate Ethers have lower boiling points compared to alcohols of comparable mass because they form dipole-dipole interaction among themselves. they cannot form hydrogen bond among themselves. they can form hydrogen bond with water. they are solvents in organic reactions. Dehydration of two molecules of methanol under acidic condition (H2SO4) at high temperature will produce * Acetone Ethanal Acetic acid Methoxymethane
- Organic Reaction Write an equation for the oxidation of each alcohol. Use [O] above the arrow to indicate an oxidizing agent. If no reaction occurs, write "no reaction" after the arrow. 1. CH3CH2CH2CH2CH2OH CH₂ CH₂CCH₂CH₂ ОН CH CHCH CH CH CH, ОНWhich is NOT a physical property of alcohols or phenols? O Phenols are generally only slightly soluble in water. O The hydroxyl group of an alcohol is nonpolar. The solubilities of normal primary alcohols in water decrease with increasing molecular weight. Boiling points of normal primary alcohols increase with increasing molecular weight.Draw the structure(s) of the major organic product(s) of the following reaction. yen H CH3Mgl 1. Dry Et₂O 2. aqueous HCI at 0°
- Which of the following reactions can be used to make the following alcohol? OH 1. LIAIH4, ether 2. H30* 1. OsO4 2. NaHSO3, H20 1. CH3CH2MgBr, ether H. 2. H3O*, H2O 1. Hg(OAc)2, H2O/THF 2. NABH4 MacBook ProCH,CH,CH,-OH Draw the structure of the product expected when each of the following alcohols is reacted with a sulfuric acid catalyst au the temperature indicated. H,SO, CH,-CH-CH, 180°C a. OH H,SO, CH, — CH—СH,—ОН 180°C b. CH; H,SO, CH-CH-OH 140°C с. CH, CH,-CH-CH,-CH, H,SO, d. 140°C d. OH4. What is the correct formula for the ester produced when ethyl alcohol, CH3CH₂-OH, is reacted i-OHD with butyric acid (CH3CH₂CH₂-C-OH) a. CH3-C-CH,CH,CH,CH, -CH₂CH₂C i-o c. CHỊCH,CH,-C-O-CH,CH, Explain your answer: Co-CHỊCH, b. CH-C-O-CH,CH,CH,CH3
- Identify whether a primary or secondary alcohol was oxidized to make each of the following compounds. a. CH,-CH,-C-CH, b. СH, — СH, —С-ОН c. CH,-CH,-C-H C-H d.53. Which statement below is incorrect? а. the smallest aldehyde has the formula HCOH b. a carbonyl carbon consists of a carbon-oxygen double bond in an aldehyde, the carbonyl carbon is always bonded to a hydrogen atom с. d. Ketones are more soluble in water than alcohols with the equiva lent number of carbons1. Write the skeletal structures of propanal, acetone and cyclohexanone. What is the major intermolecular force (IMF) found in them? Based on their major intermolecular force and molecular weight, what can you predict on their solubility in water? Chemical Name Skeletal Structures Major IMF Solubility in water Propanal Acetone Cyclohexanone 2. What is the purpose of Tollens’ test (Part B)? What is the evidence of a positive result? 3. What is the purpose of oxidation test (Part C)? What is the evidence of a positive result?