For questions 13-14, refer to the following three reactions as your "answer bank." HCI H₂ Pd/C A B 1) BH3 2) H2O2/H2O/NaOH 13. Which of the three reactions above would not be regioselective? Bubble your one answer completely. Oc ОА OB 14. Which of the three reactions above would not be stereospecific? Bubble your one answer completely. ОА OB Oc
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- Draw the major organic product(s) of the following reaction. Br CH3 H3C-C-CEC-H H NaNH2 , NH3(I) CH3CH₂-CH-CH3 • You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. ● Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. ● C P opy aste []* ? ChemDoodleⓇ TAYY <15. How many different products are possible for the following reaction? Consider both regio- and stereoisomerism. Write your answer as an integer in the box provided. HCI 16. How many different products are possible for the following reaction? Consider both regio- and stereoisomerism. Write your answer as an integer in the box provided. HCI 17. How many different products are possible for the following reaction? Consider both regio- and stereoisomerism. Write your answer as an integer in the box provided. HCI 18. How many different products are possible for the following reaction? Consider both regio- and stereoisomerism. Write your answer as an integer in the box provided. H₂, Pd/C 19. How many different products are possible for the following reaction? Consider both regio- and stereoisomerism. Write your answer as an integer in the box provided. H2, Pd/CExample: H R 11' COO- Ca ↓ NH3 L or D?
- Draw a structural formula for the substitution product of the reaction shown below. Na OCH 3 CH3OH H (+) F |||4 Use the wedge/hash bond tools to indicate stereochemistry where it exists. If more than one stereoisomer of product is formed, draw both. Separate multiple products using the + sign from the drop-down menu. • Products that are initially formed as ions should be drawn in their neutral forms. *** ? + ChemDoodleⓇ removeDraw a structural formula for the substitution product of the reaction shown below. H/ ● (CH3)3C |YY Br ΔΟ H Na • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If more than one stereoisomer of product is formed, draw both. Separate multiple products using the + sign from the drop-down menu. • Products that are initially formed as ions should be drawn in their neutral forms. SH acetone [FDraw a structural formula for the substitution product of the reaction shown below. Br Na ОCH3 H3C CH3OH • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If more than one stereoisomer of product is formed, draw both. • Separate multiple products using the + sign from the drop-down menu. • Products that are initially formed as ions should be drawn in their neutral forms. C opy aste ChemDoodle'
- NaOH но- Br +Draw a structural formula for the substitution product of the reaction shown below. ● H3C HH Br + O • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If more than one stereoisomer of product is formed, draw both. Separate multiple products using the + sign from the drop-down menu. • Products that are initially formed as ions should be drawn in their neutral forms. ▼ In [F OCH 3 -85 ? Na CN CH3CH₂OH ChemDoodleⓇ >3) Complete the following: Stereochemistry, enantio-, and regioselectivity are important. j) उ type OH Hydrogenolysis F NHMe Ο Ν NO2 Ο Ν NO2 type CO₂ N type
- Rank the compounds shown from most to least reactive in an SN2 reaction. Br O I > IV> | > |II O II > I > IV > III O III > IV > I> || O I> ||| > | > IV OIV > III > | > || CI ||| Br IV CIConsider this organic reaction: CH3-0 Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. Bri No Reaction. Click and drag to start drawing a structure. 13 XНО с оснгенз Cool H+ + H20 он Н20