A compound containing Mn, CO and Cl shows peaks at 1950 cm-2000 cm -1 in IR spectrum. Mass spectral peaks were observed at = 404, 376, 348, 320, 292, 264, 236, 208, 180, 110, 55. Metastable peaks were observed at 349-1, 322 1, 294-3, 211, 183-3, 155-8, 67-2, 27-5. Suggest the most probable fragmentation pathway and predict the molecular structure.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 14.9QAP
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A compound containing Mn, CO and Cl
shows peaks at 1950 cm-2000 cm
-1
in IR spectrum. Mass spectral peaks
were observed at
= 404, 376, 348,
320, 292, 264, 236, 208, 180, 110, 55.
Metastable peaks were observed at
349-1, 322 1, 294-3, 211, 183-3, 155-8,
67-2, 27-5. Suggest the most probable
fragmentation pathway and predict the
molecular structure.
Transcribed Image Text:A compound containing Mn, CO and Cl shows peaks at 1950 cm-2000 cm -1 in IR spectrum. Mass spectral peaks were observed at = 404, 376, 348, 320, 292, 264, 236, 208, 180, 110, 55. Metastable peaks were observed at 349-1, 322 1, 294-3, 211, 183-3, 155-8, 67-2, 27-5. Suggest the most probable fragmentation pathway and predict the molecular structure.
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