Assume the standard Gibbs free energy change or deltaGO-5.02 kl/mol for the reaction dihydroxyacetone phosphate > glyceraldehyde-3-phosphate. Calculate the deltaG for this reaction at 13.6°C when DHAP =0.47M and G3P =0.0025M in kj/mol to two decimal places.

Assume the standard Gibbs free energy change or deltaGO-5.02 kl/mol for the reaction dihydroxyacetone phosphate > glyceraldehyde-3-phosphate. Calculate the deltaG for this reaction at 13.6°C when DHAP =0.47M and G3P =0.0025M in kj/mol to two decimal places.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter16: Thermodynamics: Directionality Of Chemical Reactions

Section: Chapter Questions

Problem 106QRT

See similar textbooks

Related questions

Q: At pH 7.4, the pH of blood plasma, do the majority of protein-derived amino acids bear a net…

A: Concept introduction: Isoelectric point (pI) is defined as pH at which the protein has no net…

Q: The hydrolysis of pyrophosphate to orthophosphate drives biosynthetic reactions such as DNA…

A: Vmax. = 2800 U/ mg of enzyme 1 U = 10 μmol/15 min. 1 min. = 60 second 15 min = =60 sec.…

Q: b) The diagram below shows the fraction of glutamic acid present in each of the four forms. In the…

A: Glutamic acid is a triprotic acid with condensed formula HOOCCH2CH2CH(NH3+)COOH. We are given the…

Q: A key step in the metabolism of glucose for energy is theisomerization of glucose-6-phosphate (G6P)…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3.Please resubmit the question and…

Q: Calculate the standard free-energy for creatine-phosphate hydrolysis in a cell where: creatine-P =…

A: Endergonic reactions require an input of energy; the ∆G for that reaction will be a positive value.…

Q: which substance has the greatest entrophy H2O (l) Na(s) AgCL(s) N2(g) NaOH(l)

A: Entropy : Entropy is a measure of disorder or randomness in a system. The greater the disorder in a…

Q: H-0 CH,OH (b) NH, CH, H--0=C (b) 0-H-- (a) CH, CH, CH, CH H-C CH, CH, | (d) (CH.)4–NH, (a) CH, (d)…

A: Hydrophobic Interaction: It is a type of interaction between non-polar molecules (alkyl chains) in…

Q: If a serving of salmon contains 500.0 mg of ALA and all of it is completely oxidized via B-oxidation…

A: Given:- The α- Linolenic acid is a fatty acid. mass of ALA in a serving of salmon =…

Q: ATP → ADP + Pi (ΔG°’ = -30.5 kJ/mol) In cells, the [ATP] is 0.5 mM, the [ADP] is 4.5 mM, and the…

A: Given reaction is ATP → ADP + Pi (ΔG° = -30.5 kJ/mol) Given that [ATP] = 0.5 mM [ADP] = 4.5 mM…

Q: Reaction of a reducing sugar with an alkaline solution of cupric ion (Fehling's solution) yields…

A: The explanation is given below-

Q: Name the following

A: The following is to be named:

Q: True or False An essential amino acid is one which is not synthesized in the body and thus must be…

A: 1.) An essential amino acid is one which is not synthesized in the body and thus must be supplied in…

Q: What is AG° for the conversion of glucose into lactic acid? CH1206laq). 2CH,CH(OH)COOH(ag) kJ

A: Thermodynamics is the branch of chemistry that mainly deals with the heat transfer between system…

Q: The conversion of glucose (C&H1206) into lactic acid (2CH3CH(UH)COUH) drives the phosphorylation OF…

A: The conversion of glucose to lactic acid can be represented as C6H12O6 (aq) → 2 CH3CH(OH)COOH (aq)…

Q: Explain the difference in the melting points of the palmitic acid and stearic acid:

A: Melting point :- When a solid is heated , it melts to form a liquidThe temperature at which a…

Q: The metabolism of glucose produces CO2 and H2O, how does the human body expect these reaction…

A: The metabolism of glucose produces CO2 and H2O. These have to be expelled from the body.

Q: When the terminal phosphate is cleaved from the adenosine triphosphate molecule, the products are…

A: ATP hydrolysis is the catabolic reaction by which chemical energy that has been stored in the high…

Q: Define kilocalorie. State the number of kilocaloriessupplied by a gram of carbohydrate, a gram of…

A: a calorie unit is used to express the energy. The calorie is the amount of heat required to raise…

Q: What is the standard free energy change (AG"), for the reduction of coenzyme Q by NADH as carried…

A: The question is based on the concept of redox reactions reactions. Reactions in which simultaneous…

Q: Create a schematic diagram flowchart to separate the components of the mixture: CO2, Sugar, H2O, and…

A: Separation of carbon dioxide, water, sugar and citric acid. Carbon dioxide is separated from the…

Q: MgNH4PO4 6H2O which is heated to between 40 and 60 ºC loses part of its waters of hydration:…

A: The atomic mass of phosphorous is 30.97 g/mol and the molar mass of MgNH4PO4 • H2O is 155.33 g/mol.

Q: what is isoelectric ph and calculate for glutamic acid?

A: A point where molecule carried no net charge called isoelectric point.

Q: Explain which chemical species of ascorbic acid (C6H8O6) and citric acid (C6H8O7) are present at the…

A: An acid is a chemical substance that can furnish hydrogen ions (H+) in the aqueous solution. When…

Q: Which compound in each of the following pairs of phosphate-containing compounds releases more free…

A: (a)ATP and Phosphoenolpyruvate: The free energy released on hydrolysis of ATP is -7.7kcal/mol. The…

Q: .) Explain the observed pH of the solutions of the amino acids glutamic acid and lysine.

A: Since you have posted multiple questions as per guidelines we can answer only one per session . If…

Q: Yeast is used as a leavening agent in bread-baking. In the presence of oxygen, the yeast feeds on…

A: a. The balanced chemical equation to produce ethanol and carbon dioxide from glucose is:…

Q: What is the Ksp for Ag2CrO4? Write the equation for the dissolving of solid Ag2CrO4 in water?…

A: Solution of above question are below

Q: Consider the reaction in producing wine: CsH12O6(aq) → 2C;H;OH§[aq) + 2CO2(aq). When zymase is added…

A: We need to find out the role of zymase in given reaction.

Q: 5) The conversion of dihydroxyacetone phosphate (DHAP) to glyceraldehyde-3-phosphate in glycolysis…

A: As per our company guidelines we are supposed to answer only one question. Kindly repost other…

Q: The fully protonated form of the amino-acid glycine (R=H) may be simply written as H2Gly+. Write the…

A: Glycine is the simplest stable amino acid, with the chemical formula NH₂‐CH₂‐COOH. Glycine is an…

Q: COMPOUND THAT CHEMICAL TEST WILL TEST POSITIVE C. HO ОН 3-pentanol pentanol d. OH

A: Lucas test is used to differentiate primary, secondary and tertiary alcohols. Lucas reagent is a…

Q: ATP + H2O ––> ADP + Pi where Pi stands for the various forms of phosphate that exist at the pH…

A: ATP hydrolysis is the catabolic reaction by which chemical energy that has been stored in the high…

Q: Numerous acidic species are found in living systems. Write the proton transfer equilibria for the…

A: An acid is a substance that gives H+ ions in its solution whereas a basic substance gives OH- ions…

Q: Write the equilibrium -constant expression for the reaction shown in terms of [A], [B], [C] and D.…

A: Given Reaction, A(g)+B(g) ---------> 2C(g)+D(g)

Q: pick the substance and conditions which would have the higher entropy. a) fructose (C6H12O6) b)…

Q: Two compartments are separated by a semi- permeable membrane. In the left hand compartment is the…

Q: Running a mile in ten minutes burns between 100 and 120 calories for a 150-pound person. For the…

A: Given :- Running a mile in ten minutes burns between 100 and 120 calories for a 150-pound person.…

Q: Which chemical group contributes a negative molecule and when transferred, it increases a molecule's…

A: Answer - The correct option is (b) - amino Explanation - According to the question - Amino which…

Q: Choose any amino acid and show, by diagrams of your own creation, how pH will modify the charge…

Q: Calculate the standard free-energy change for each of the following metabolically important…

Q: Formation of glycerol 3-phosphate is a model reaction for many metabolic processes. The ΔG˚’ for…

Q: The hydrolysis of pyrophosphate to orthophosphate drives biosynthetic reactions such as DNA…

A: Given, 1U = 10 μmol PPi/ 15 min (for the enzyme). Vmax = 2800 U/mg enzyme.

Q: All amino acids have two ionizable functional groups: an a-amino group (average pK, of 9.4) and an…

A: The deprotonation of an acidic group takes place at a pH higher than the pKa value. Hence the…

Q: lthough the ATP-ADP reaction is the principle energy shuttle in metabolic pathways, many other…

A: Given : We have to tell whether we can combine the reactions.

Q: The standard free energy change (ΔG°') for hydrolysis of fructose-l,6-bisphosphate (FBP) to…

Q: Consider the following table of Ksp values.Which one of the compounds shown in the table is the…

A: We have to predict the compound with least soluble property.

Question

100%

Assume the standard Gibbs free energy change or deltaGO=5.02 kJ/mol for the reaction dihydroxyacetone phosphate <> glyceraldehyde-3-phosphate. Calculate the deltaG for this reaction at 13.6°C when DHAP =0.47M and
G3P =0.0025M in kJ/mol to two decimal places.
«< Question 25 of 28
A Moving to another question will save this response.
Close Window

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Plants synthesize carbohydrates from CO2 and H2O by the process of photosynthesis. For example, 6CO2(g)+6H2O(l)C6H12O6(aq)+6O2(g) G=2.87103 kJ at pH 7.0 and 25°C. What is K for the reaction at 25°C?
Glycolysis is the process by which glucose is metabolized to lactic acid according to the equation C6H12O6(aq)2C3H6O3(aq) G=198 kJ at pH 7.0 and 25°C Glycolysis is the source of energy in human red blood cells. In these cells, the concentration of glucose is 5.0103 M, while that of lactic acid is 2.9103 M. Calculate AG for glycolysis in human blood cells under these conditions. Use the equation G=G+RT In Q, where Q is the concentration quotient, analogous to K.
Suppose you have an endothermic reaction with H = + 15 kJ and a S of 150 J/K. Calculate G and Keq at 10, 100, and 1000 K.
at 25oC, Ka for aspirin (C9H8O4) is 3.0 x 10-4. Calculate Δ Go (kJ/mol) for the reaction: C9H8O4(aq) + H2O(l) = H3O+(aq) + C9H7O4-(aq)
For the triose phosphate catalyzed reaction: dihydroxyacetone phosphate <--> glyceraldehyde-3-phosphate the standard change in Gibbs free energy is ΔG'º=7.53 kJ/mol. Calculate the ΔG for this reaction at 298K when the concentration of dihydroxyacetone phosphate is 0.161 M and the concentration of glyceraldehyde-3-phosphate is 0.00163 M.
Calculate the AH°, for the combustion of ethene using the given AH° : run C2 H4 (g) + 302 (g) 2H;0 (1) + 2CO;(g) AH°, ethenelg) = 52.4 kJ/mol %3D AH°, water() = -285.8 kJ/mol AH°, carbon dioxide(g) = -393.5 kJ/mol O - 1.41 x10 kJ/mol O-7.63 x103 kJ/mol O - 3.25 x103 kJ/mol
Calculate AG° and AS°at 25 °C for the following fermentation reaction: 2. C,H1206(aq) → 2C2H;OH(aq) + 2C02(9) AG° (C,H1206, aq) = -910.4 kJ/mol AH°; (C,H1206,aq) = -1273.3 kJ/mol AG°; (C,H5OH,aq) = -181.64 kJ/mol AH°;(C2H50H,aq) = -288.3 kJ/mol AG°; (CO2,g) = -394.36 kJ/mol AH° (CO2,g) = -393.51 kJ/mol Note: Be mindful that we read all of your submissions individually. Corresponding deductions will be applied to students with the same output if plagiarism is detected.
The hydrolysis of ATP to form ADP requires energy to break the bonds initially, but releases moreenergy as bond are remade making the reaction exothermic overall. The Gibbs free energy for thisreaction is -30.5 kJ/mole, meaning that it is also exergonic (ΔG=-). This energy can be used by otherbiological systems if this reaction is coupled with another less favorable one. In this case, the creation ofglucose-6-phosphate, C6H10O9P, this is a pivotal intermediate in many biochemical pathways. PO43- + C6H12O6 ⇌ H2O + C6H10O9P ΔG° = +13.8 kJ/moleATP + H2O ⇌ ADP + PO43- ΔG° = -30.5 kJ/mole A) What is the overall reaction that takes place? B) Calculate the ΔG° for this reaction C) Will this be a successful coupled reaction?
Given that the reaction of 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 3 H20 (g) ΔΗ - - 906 kJ What would AH for NO (g) + ? H20 (g) → NH3 (g) + O2 (g) be? 2. 906 kJ 226.5 kJ -226.5kJ 453 kJ
Consider the coupled reactions: kcal AGO'= -16.3 mol 1,3-ВPG 3-PG + Pi AG°'= -7.3 kcal mol ATP → ADP + P; What is the net reaction? 3-PG + ADP + Pi→ 1,3-BPG + ATP 3-PG + ATP → 1,3-BPG + ADP + P¡ O 1,3-BPG + ADP + P¡ –→ 3-PG + ATP O 1,3-BPG + ATP → 3-PG + ADP + P¡
Given the data below, H°, for the reaction rxn 2SO2 (g) + O2 (g) → 2SO3 (g) is kJ. AH°; (SO2 (g)) = -297 kJ/mol AH°; (SO3 (g)) = -396 kJ/mol AH°; (SO2C12 (g)) = -364 kJ/mol AH°f (H2SO2 (1)) = -814 kJ/mol AH°; (G2O (1)) = -286 kJ/mol %3D O The AH°F of O2 (g) is needed for the calculation. 99 198 -198 -99
For the aqueous reaction CH2OH Н—С—он ČH2-0- CH2-0-P-0- dihydroxyacetone phosphate = glyceraldehyde–3 –phosphate the standard change in Gibbs free energy is AG°' = 7.53 kJ/mol. Calculate AG for this reaction at 298 K when [dihydroxyacetone phosphate] = 0.100 M and [glyceraldehyde-3-phosphate] = 0.00500 M. AG = kJ/mol