Ammoniacal nitrogen can be determined by treatment of the sample with chloroplatinic acid; the product is slightly soluble ammonium chloroplatinate: H 2 PtCl 6 + 4NH 4 + → (NH 4 ) 2 PtCl 6 + 2H + The precipitate decomposes on ignition, yielding metallic platinum and gaseous products (NH 4 ) 2 PtCl 6 → Pt(s) + 2Cl 2 (g) + 2NH 3 (g) + 2HCl(g) Calculate the percentage of ammonia in a sample if 0.325g gave rise to 0.653g of platinum

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Chapter21: Chemistry Of The Main-group Elements
Section: Chapter Questions
Problem 21.188QP: Sodium perchlorate, NaClO4, is produced by electrolysis of sodium chlorate, NaClO3. If a current of...
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  1. Ammoniacal nitrogen can be determined by treatment of the sample with chloroplatinic
    acid; the product is slightly soluble ammonium chloroplatinate:
    H 2 PtCl 6 + 4NH 4 + → (NH 4 ) 2 PtCl 6 + 2H +
    The precipitate decomposes on ignition, yielding metallic platinum and gaseous products
    (NH 4 ) 2 PtCl 6 → Pt(s) + 2Cl 2 (g) + 2NH 3 (g) + 2HCl(g)
    Calculate the percentage of ammonia in a sample if 0.325g gave rise to 0.653g of platinum.
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