A student wishes to determine the chloride ion concentration in a water sample at 25 \deg C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e > Ag O + Cl(aq) E\deg red = 0.2223 V And a copper electrode with 0.500 M Cu^2* as the second half cell Cu^2+ (aq) + 2 e > Cu(s) E\deg red= 0.337 V The measured cell potential when th water sample was placed into the silver side of the cell was 0.0781 V. Given the standard cell potential for this cell is 0.115 V, and the measured cell potential is 0.0781, what is the concentration chloride ions in the solution?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.103QE
icon
Related questions
Question
A student wishes to determine the chloride ion concentration in a water sample at 25 \deg C using a galvanic cell constructed with a graphite electrode and a half - cell of AgCl(s) + e¯ - > Ag(s
) + Cl(aq) E\deg red = 0.2223 V And a copper electrode with 0.500 M Cu^2+ as the second half cell Cu^2+ (aq) + 2 e¯ - > Cu(s) E\deg red = 0.337 V The measured cell potential when the
water sample was placed into the silver side of the cell was 0.0781 V. Given the standard cell potential for this cell is 0.115 V, and the measured cell potential is 0.0781, what is the concentration of
chloride ions in the solution?
Transcribed Image Text:A student wishes to determine the chloride ion concentration in a water sample at 25 \deg C using a galvanic cell constructed with a graphite electrode and a half - cell of AgCl(s) + e¯ - > Ag(s ) + Cl(aq) E\deg red = 0.2223 V And a copper electrode with 0.500 M Cu^2+ as the second half cell Cu^2+ (aq) + 2 e¯ - > Cu(s) E\deg red = 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0781 V. Given the standard cell potential for this cell is 0.115 V, and the measured cell potential is 0.0781, what is the concentration of chloride ions in the solution?
Expert Solution
steps

Step by step

Solved in 4 steps with 3 images

Blurred answer
Knowledge Booster
Electrochemical Cells
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning