4. Calculate the standard heat of formation of calcium carbide (CaC) from its elements in kJ/mol using the following thermochemical equations. (hint come up with the overall equation first) Ca+ 2H₂O ⇒ Ca(OH)2 + H₂ 2C+0⇒ 2CO CaO + H₂O⇒ Ca(OH)200 2H₂ + O⇒ 2H₂O CaO + 3C = CaC + CO ΔΗ°= - 414.79 kJ ΔΗ°= - 221.00 kJ ΔΗ°= - 65.19 kJ ΔΗ°= - 571.80 kJ ΔΗ°= + 462.30 kJ

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Chapter6: Thermochemisty
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4. Calculate the standard heat of formation of calcium carbide (CaC) from its elements in kJ/mol using the
following thermochemical equations.
(hint come up with the overall equation first)
Ca(s) + 2H₂O ⇒ Ca(OH)2(s) + H₂(g)
2C(s) + O2(g) → 2CO
CaO + H₂O⇒ Ca(OH)2()
2H2(g) + O2(g) → 2H₂O)
CaO) + 3C,,→ CaCs) + CO
ΔΗ°= - 414.79 kJ
ΔΗ°= - 221.00 kJ
ΔΗ°= - 65.19 kJ
ΔΗ°= - 571.80 kJ
AH°= + 462.30 kJ
1
Transcribed Image Text:4. Calculate the standard heat of formation of calcium carbide (CaC) from its elements in kJ/mol using the following thermochemical equations. (hint come up with the overall equation first) Ca(s) + 2H₂O ⇒ Ca(OH)2(s) + H₂(g) 2C(s) + O2(g) → 2CO CaO + H₂O⇒ Ca(OH)2() 2H2(g) + O2(g) → 2H₂O) CaO) + 3C,,→ CaCs) + CO ΔΗ°= - 414.79 kJ ΔΗ°= - 221.00 kJ ΔΗ°= - 65.19 kJ ΔΗ°= - 571.80 kJ AH°= + 462.30 kJ 1
Selected Standard Molar Enthalpies of Formation
AH₁
AH;
AH₁
Substance (kJ/mol) Substance (kJ/mol) Substance (kJ/mol)
Al₂O3(s)
-1675.7 HBr(g)
CaCO3(s)
-1207,6 HCl(g)
CaCl₂(s)
Ca(OH)₂(s)
CCL₂(E)
CCL4(8)
CHCI ()
CH₂(g)
C₂H₂(g)
C₂H₁(g)
C₂H₂(g)
CzHs(g)
CH()
CH₂OH(E)
C₂H₂OH()
CO(g)
CO₂(g)
COCI₂(g)
+49.1 Fe₂O₂(8)
-239.2 Fe,O4(s)
-277.6 FeCl₂(s)
CH3COOH(E) –484.3 FeCls(s)
-110.5 FeS (8)
CS₂(e)
CS₂(g)
CrCla(g)
Cu(NO₂)₂ (8)
-795.4 HF(g)
-985.2 HCN(g).
-128.2 H₂O(E)
-95.7 H₂O(g)
CuO(s)
CuCl(s)
CuCl₂(s)
-134.1 H₂O₂(e)
-74.6 HNO (0)
+227.4 H₂PO4(s)
+52.4 H₂S(g)
-84.0 H₂SO4(e)
-103.8 FeO(s)
–36.3|NH(8)
-92.3 N₂H4(e)
-273.3 NH Cl(s)
+135.1 NH₂NO(s)
-285.8 NO(g)
-393.5 PbCl₂(s)
-219.1 MgCl₂(s)
+89.0 MgO(s)
+116.7 Mg(OH)2(s)
-556.5 HgS(s)
-241.8 NO₂(g)
-187.8 N₂O(g)
-174.1 N₂O(g)
1284.4 PH,(g)
-20.6 PCl₂(g)
814.0 P,O,(s)
-272.0 P4O₁0(s)
-824.2 KBr(s)
-1118.4 KCl(s)
-341.8 KCIO,(s)
-399.5 KOH(s)
-178.2 AgaCO₂ (s)
-359.4 AgCl(s)
-641.3 AgNO,(s)
-601.6 Ag S(s)
-924.5 SFB(g)
-58.2 SO₂(g)
-302.9 NaCl(s)
-411.2 SO₂(g)
-157.3 NaOH(s)
-425.6 SnCl₂(s)
-137.2 Na₂CO3(s)-1130.7 SnCl4(e)
-220.1
-45.9
+50.6
-314.4
-365.6
+91.3
+33.2
+81.6
+11.1
+5.4
-287.0
-2144.3
-2984.0
-393.8
-436.5
-397.7
-424.6
-505.8
-127.0
-124.4
-32.6
-1220.5
-296.8
-395.7
-325.1
-511.3
Note: The enthalpy of formation of an element in its standard state is
defined as zero.
Transcribed Image Text:Selected Standard Molar Enthalpies of Formation AH₁ AH; AH₁ Substance (kJ/mol) Substance (kJ/mol) Substance (kJ/mol) Al₂O3(s) -1675.7 HBr(g) CaCO3(s) -1207,6 HCl(g) CaCl₂(s) Ca(OH)₂(s) CCL₂(E) CCL4(8) CHCI () CH₂(g) C₂H₂(g) C₂H₁(g) C₂H₂(g) CzHs(g) CH() CH₂OH(E) C₂H₂OH() CO(g) CO₂(g) COCI₂(g) +49.1 Fe₂O₂(8) -239.2 Fe,O4(s) -277.6 FeCl₂(s) CH3COOH(E) –484.3 FeCls(s) -110.5 FeS (8) CS₂(e) CS₂(g) CrCla(g) Cu(NO₂)₂ (8) -795.4 HF(g) -985.2 HCN(g). -128.2 H₂O(E) -95.7 H₂O(g) CuO(s) CuCl(s) CuCl₂(s) -134.1 H₂O₂(e) -74.6 HNO (0) +227.4 H₂PO4(s) +52.4 H₂S(g) -84.0 H₂SO4(e) -103.8 FeO(s) –36.3|NH(8) -92.3 N₂H4(e) -273.3 NH Cl(s) +135.1 NH₂NO(s) -285.8 NO(g) -393.5 PbCl₂(s) -219.1 MgCl₂(s) +89.0 MgO(s) +116.7 Mg(OH)2(s) -556.5 HgS(s) -241.8 NO₂(g) -187.8 N₂O(g) -174.1 N₂O(g) 1284.4 PH,(g) -20.6 PCl₂(g) 814.0 P,O,(s) -272.0 P4O₁0(s) -824.2 KBr(s) -1118.4 KCl(s) -341.8 KCIO,(s) -399.5 KOH(s) -178.2 AgaCO₂ (s) -359.4 AgCl(s) -641.3 AgNO,(s) -601.6 Ag S(s) -924.5 SFB(g) -58.2 SO₂(g) -302.9 NaCl(s) -411.2 SO₂(g) -157.3 NaOH(s) -425.6 SnCl₂(s) -137.2 Na₂CO3(s)-1130.7 SnCl4(e) -220.1 -45.9 +50.6 -314.4 -365.6 +91.3 +33.2 +81.6 +11.1 +5.4 -287.0 -2144.3 -2984.0 -393.8 -436.5 -397.7 -424.6 -505.8 -127.0 -124.4 -32.6 -1220.5 -296.8 -395.7 -325.1 -511.3 Note: The enthalpy of formation of an element in its standard state is defined as zero.
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