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- The two pentene isomers react with mCPBA, followed by an aqueous workup with NaOH/H2Ó. Draw the key reaction intermediates and the product(s); use arrow pushing to explain the stereochemical outcomes of the reactions Intermediate Final Products MCPBA CO2OH mCPBA NaOH/H2O CI Intermediate Final Products MCPBA NaOH/H2O 6.For the following reaction, decide whether a solution of the products would be optically active or not and why. You will need to know the product of this reaction in order to solve this problem. To preview the image click here Br CH3 Na: CEN: acetone O Not optically active, achiral product is formed O Not optically active, racemic mixture is formed O Not optically active, a meso compound is formed O Optically active, a single enantiomer is formedWhen treated with NaOH, the bromide below gives an alkene by the E2 mechanism, by elimination of the H atom indicated by the arrow: (a) Draw the Newman projection from which elimination takes place. (b) Draw the mechanism. (c) Draw the product with the proper stereochemistry. (d) Assign the proper stereochemical descriptor to the product. (e) Give the rate equation
- Draw the mechanism, including stereochemistry, of the following reaction, predicting the products formed. What is the relationship of the products that are formed?For eaach image, predict the MAJOR product(s). Show stereochemistry where applicable and draw out ALL stereoisomers formed (as major products) in each reaction. State the mechanism(s) by which the major product(s) are formed (SN1, SN2, E1, and/or E2). Reagents are NOT present in excess.Consider the following reaction. CH3CH₂CH=CHCOH HCI CH3CH₂CH CHCOH c₁ CH3CH₂CH- H O CHCOH H CI this product is not observed Account for the fact that this reaction yields only a single product by drawing the carbocation intermediate leading to the observed product.
- Under acid-catalyzed conditions, epoxides can be opened by a variety of nucleophiles other than water, such as alcohols. In such a case, the nucleophile will generally attack at the more substituted position. Using this information, predict the products for each of the following reactions (a-b): ? 1) RCO-H 2) [H₂SOJ Modify the given structure to draw the major product(s). Use the single bond tool to interconvert between double and single bonds. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. CH₂ Edit Drawing AWhen treated with NaOH, the bromide below gives an alkene by the E2 mechanism, by eliminationof the circled atoms: (a) Draw the Newman projection from which elimination takes place. (b) Draw the mechanism. (c) Draw the product with the proper stereochemistry. (d) Assign the proper stereochemical descriptor to the product. (Z, E? Trans,CiS?) (e)What would happen to the stereochemistry of the product if the enantiomer of the starting material were used inthe reaction?Predict the major products of the following reaction. Be sure to use wedge and dash bonds to show the stereochemistry of the products when it's important, for example to distinguish between two different major products.
- For each reaction, draw the complete mechanism and the major organic product(s), paying attention to stereochemistry. (a) (b) OH LOH (еxcess) ? ? CH,Cl2 CH2CI2In the presence of light or heat, diazomethane (CH,N2) creates a carbene, which then adds to an alkene to make a cyclopropane. In the boxes below. draw the mechanism arrows for the reaction. H INEN: INE N:Draw the mechanism for the following reaction and account for the relative stereochemistry. MeO₂C MeO₂C CO₂Me Pd2(dba)3.CHCI 3 Ph3P, ACOH MeO₂C