Draw major onganic Product *should haNY. shruschumistry * consider stureachemical iapacts in reactant. strric hinderance. CL-3 Such as CH 3 a CH3 2) H202) CH3 Brz> H20 CH3
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- (vi) Explain the differing reactivity in the two reactions below: H2/Pt Mn Cal CO 1 At., RT. Cal CO CH2 CH2 4 H2 [(H,C=CH)PtCl2k 1 At., RT. 2 C2H6 +2 Pt +4 HCPage of 11 ZOOM + Section A (continued) A18. Give suitable nucleophiles (1 and 2) for the following organic reactions: 1 2 H3C H3C OMe H3C 1 = MEOH; 2 = NH3 1 = H2O; 2 = NH2ET 1 = NaOMe; 2 = NH2ME 1 = MEOH; 2 = NH2ET %3D %3D В %3D %3D A19. How would you categorize the atoms labelled in the figure below? H2N CH3 Atom B Atom A Both atom A and atom B are electrophilic Atom A is nucleophilic; Atom B is electrophilic Both atom A and atom B are nucleophilic Atom A is electrophilic; Atom B is nucleophilic A B A20. Rank the following acids from highest to lowest pKa. CI CI F CH3 Но HO CI HỌ Но CI A C D А A>D>B> C C>D>B>A C A >B> D> C C > B >D> A 明 ABCMind Tap - Cengage Learnin X G To analyze the reaction, firs X Heploymentid=5735112480241329813180832311&eISBN=9781305862883&id=1774598910&snapshot!... Bb DO: MLM HW 2.5- Blackb X At a pressure of 1 atm, point of 78.4 °C. The following information is given for ethanol, C₂H5OH, at 1 atm: boiling point = 78.4 °C AHvap (78.4 °C) = 38.6 kJ/mol AHfus(-115 °C) = 5.02 kJ/mol melting point = -115 °C specific heat liquid = 2.46 J/g°C Submit Answer References Use the References to access important values if needed for this question. Change Energetics: This is group attempt 1 of 10 Bb My Blackboa Autosaved at 9:15 PM Q kj of heat are needed to vaporize a 34.8 g sample of liquid ethanol at its normal boiling
- The followmg reacthon was studied at 25 C in henzene solution containing 0.1 M pyridine. CH.OH + (CH.),CCI CH,OC(C,H), IICI The following setx of data were observed Inihal concentiation AL, min Final C), M [B, M 0.05 IC M 0.0000 0.10 25 0.0033 0.0039 0.0077 0.10 0.10 15.0 0 10 0.20 O Whut ratc law is consistent with the above dau undhat ix the hest avernge valuc fo the rate constani, expressed in seconds and molur conceniration units? 0.0000 7.5 Ansuer: O Roode law: k[AJ[B] O Averoge value rade Constant -3. -1 =4.335X10 M's"Calculate delt G for a.) CH3NH2(aq) + H2O (l) -> CH3NH3+ (aq) + OH-(aq) T= 25C kp= 4.4x 10-4 b.) Pbl2(s) + Pb2+(aq) +2I-(aq) T= 25C Kp= 8.7x10-9What is meant by kinetic study? How USP define stability of the product? Enlist the factors which affect directly or indirectly the stability of pharmaceutical and at least three objectives of stability studies for pharmaceutical products?
- Which of the Allwing Paren thesis) has the highest molor heat Cupacity a) Glyeine (97A) 6) Alanıne (121 A) f Leucine (1AI A) Phunylalanıne (228 n") S Tryptophan (204 A) Omino aud residues (accessible surfaa area in In water?(c) (d) Н (e) НО HO ОН н Na₂Cr₂O7 H2SO4, H2O 1. LiAIH4 2. H2O workup 3. PCC 4. (Ph)3PCH2 OH H2SO4 (catalytic)When the followling reaction is at equilbrlum, which of these relationships is always true? 2 O3(g) = 302(9) Muliple Choice O Kdo22 - 1033 O 1032-102 O 103l-(02) O Kdoa? - 102
- Which of the following represents the correct transition state for a hydroboration reaction mechanism (use the correct number or your answer: 1, 2, 3, or 4)? Also, answer any follow-up questions. Anne + BH₂ CH₂ H₂B----H Hiine. R 2 CH₂ H 3 ansition state of hydroboration is best described by structure number -CH₂ "do e term (one word) that describes the stereocontrol of the hydroboration reaction? te da term that describes the regiocontrol of the hydroboration reaction? the term (one word) that best describes how the bonds are broken and formed in the first step of a hydroboration ism? 4 BH₂ CH₂2 hp10. What is the major organic product generated in the reaction below? HO HO 40||!!!!!! (A) OH ...... (B) 1) 03 2) (CH3)2S HO O (C) H НО. (D)COCI, (g) = CO (g) + Cl, (g) @ 100 °C К. %3D 2.19 х 10-10 Predict the direction the rxn proceeds toward equilibrium for the following mixture: [COCL,]= 0.0100 M [CO] = [Cl,]=1.48 x 10-6 M %3D