1. Give the structures of the products obtained when the following are heated. Ph Me OMe b. a. O,N Ph NC CN d.

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Diels-Alder Reaction
1. Give the structures of the products obtained when the following are heated:
Ph
Me
OMe
b.
a.
+
O,N
Ph
C.
NC
CN
d.
2 Which compounds would you heat together in order to synthesize each of the
following?
CHO
3. The 1,4-diphenyl-1,3-butadiene that you used is the (E,E)-isomer. The phenyl
groups in your product are cis with respect to each other. USING
STEREOCHEMICAL FORMULAS, explain why the (E,E)- diene gives an adduct
in which the phenyl groups are cis. (HINT: Remember that there is free rotation
around single bonds, and study the discussion of the stereochemistry of the
Diels-Alder reaction in your text.)
Transcribed Image Text:Diels-Alder Reaction 1. Give the structures of the products obtained when the following are heated: Ph Me OMe b. a. + O,N Ph C. NC CN d. 2 Which compounds would you heat together in order to synthesize each of the following? CHO 3. The 1,4-diphenyl-1,3-butadiene that you used is the (E,E)-isomer. The phenyl groups in your product are cis with respect to each other. USING STEREOCHEMICAL FORMULAS, explain why the (E,E)- diene gives an adduct in which the phenyl groups are cis. (HINT: Remember that there is free rotation around single bonds, and study the discussion of the stereochemistry of the Diels-Alder reaction in your text.)
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