Predict the intermediate 1 and final product 2 of this organic reaction: Billsea NaOMe You can draw 1 and 2 in any arrangement you like. 1 H+ 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center.
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- Draw the structure of the organic product of the reaction between cyclohexene and Q3 then (CH3)2S. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. Separate multiple products using the + sign from the drop-down menu. • In cases where there is more than one answer, just draw one. ● TAYY ChemDoodleⓇ Sn [F5. Provide the major organic products of the following reactions. Use dashed and wedged bonds to represent the configuration of chiral centers. (f) 1. BH3 THF 2. HO', H2O2Predict the intermediate 1 and final product 2 of this organic reaction: вом You can draw 1 and 2 in any arrangement you like. NaOMe H+ 1 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center.
- Draw a resonance structure, complete with all formal charges and lone (unshared) electron pairs, that shows the resonance interaction of the acetoxy with the para position in phenyl acetate. phenyl acetate ● CH3 • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. In cases where there is more than one answer, just draw one. Sn [F ?1. OsO4 2. NaHSO3 In the box below draw the structure of the organic product(s) of this reaction. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Show stereochemistry in a meso compound. • If the reaction produces a racemic mixture, draw both stereoisomers. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. opy aste ChemDoodle >a. Draw and name all of the isomeric products obtainedfrom the monobromination of propane with Br2/light. If halogenation were a completely randomreaction and had an equal probability of occurring atany of the C—H bonds in a molecule, what percentage of each of these monobromo products would beexpected?b. Answer part (a) using 2-methylpropane as the starting material.
- Draw the organic product(s) of the following reaction. CH3 CH3 H₂C-C-CEC-C-CH3 CH3 CH₂ • You do not have to consider stereochemistry. • Include cationic counter-ions, e.g., Nat in your answer, but draw • If no reaction occurs, draw the organic starting material. Separate multiple products using the + sign from the drop-dow II... ? NaNH, / NH3(I) ChemDoodle SHIFDraw the product(s) of the following reactions. H2 Lindlar catalyst CH;CH2-CEC-CH3 Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ChemDoodle >Draw the product(s) of the following reactions. CH3(CH₂)7-CEC-(CH₂)7-C Y [*** OH • Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. H₂C=CH₂ H₂ Lindlar catalyst O $ [ ] كر [References] ChemDoodle Prev
- Cyclic forms of D-glucose: Furanose and Pyranose Recall that aldehyde and alcohol react to form hemiacetal. The O in OH acts as nucleophile, attacking the partially positive C of C=O. The H from the OH of alcohol is transferred to the O of C=O. он R R1 HO, On the other hand, ketone and alcohol also react to form hemiketal. OH R R2 R R1 HO, In glucose the OH in C-4 or C-5 can react with the C=O. If the C-4 OH reacts with the C=O the structure is a furanose (5-membered ring); if C-5 OH the product is a pyranose (6-membered ring). Furanose and pyranose are derived from cyclic ethers furan and pyran. Both furanose and pyranose have two isomers: the alpha and beta (also called anomers). Furan Pyran Furanose and pyranose form of D-glucose (note the numbering of carbon atoms) Furanose (5-membered ring) Alpha Pyranose (6-membered ring) Alpha Beta Beta 1 HO- Но H- Но H- _2 FH- H- OH FHO- H HO. но- H- но- H. Но Но H-4 H_5. FHO- FHO- H OH 6CH2OH H CH,OH CH,OH CH2OH C-1 OH is on the right Alpha-D-…Draw a structural formula for 2,3-dimethylbutanoic acid. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. 0- 8) // CH4 OG It's [ ] در ? ChemDoodle1) RCO H 2) [H₂SOJ. ? Modify the given structure to draw the major product(s). Use the single bond tool to interconvert between double and single bonds. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. H₂C. OH th CH, CH₂ OH H₂C OH aff CH₂ CH₂ Edit Drawing