II) a-Draw the proper Haworth form and most stable chair conformation for ß-anomer of L-mannopyranose. b- Write the systematic name of this compound

Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Mark S. Cracolice, Ed Peters
Chapter21: Organic Chemistry
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Problem 99E
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II) a-Draw the proper Haworth form and most stable
chair conformation for ß-anomer of L-mannopyranose.
b- Write the systematic name of this compound
III) What are the principal organic products when
L-Gulose is treated under the following conditions?
Mechanisms are not necessary.
a.) Ac₂O, H₂O* b.) MeOH, H3O*
c.) Br₂/H₂O
d.) 1.) NaCN 2.) H₂/Pd 3.) H₂O e.) 1.) NH₂OH 2.)
Ac₂O/Py 3.) CH3ONa
f.) NaBH4/H₂O g.) Tollen's reagent
HO-
HO
H
H
O
H-
HO-
-H
-H
-OH
-OH
CH₂OH
I
D-Mannose
HO- -H
HO
-H
-OH
-H
-OH
L-Gulose
Transcribed Image Text:II) a-Draw the proper Haworth form and most stable chair conformation for ß-anomer of L-mannopyranose. b- Write the systematic name of this compound III) What are the principal organic products when L-Gulose is treated under the following conditions? Mechanisms are not necessary. a.) Ac₂O, H₂O* b.) MeOH, H3O* c.) Br₂/H₂O d.) 1.) NaCN 2.) H₂/Pd 3.) H₂O e.) 1.) NH₂OH 2.) Ac₂O/Py 3.) CH3ONa f.) NaBH4/H₂O g.) Tollen's reagent HO- HO H H O H- HO- -H -H -OH -OH CH₂OH I D-Mannose HO- -H HO -H -OH -H -OH L-Gulose
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