A conductivity test of a dilute solution of nitrous acid (HNO 2(aq)) has very low electrical conductivity (the bulb on the tester glows dimly) and the pH is measured to be about 4. The same concentration of a nitric acid (HNO3(aq)) solution makes the conductivity tester’s bulb glow brightly and has a pH of less than 1. Explain the difference between these two acids.

Fundamentals Of Analytical Chemistry
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Author:Skoog
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Chapter13: Titrations In Analytical Chemistry
Section: Chapter Questions
Problem 13.5QAP
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1. A conductivity test of a dilute solution of nitrous acid (HNO 2(aq)) has very low electrical conductivity (the bulb on the tester glows dimly) and the pH is measured to be about 4. The same concentration of a nitric acid (HNO3(aq)) solution makes the conductivity tester’s bulb glow brightly and has a pH of less than 1. Explain the difference between these two acids.

 

2. Design an experiment using sequential qualitative analysis to determine whether a solution contains acetate or carbonate ions. Include both written instructions and a diagram of your experiment. For each stage of the test, write net ionic equations for the reaction that produces the precipitate.

 

3. Use the following experimental titration data to calculate the concentration of the acid being analysed.

Observations: The initial solution of acetic acid (HC2H3O2) is clear and colourless. A few drops of phenolphthalein indicator are added to each sample. A dilute solution of sodium hydroxide (concentration 2.50 x 10-4 mol/L) is used as the titrant. As the mixture reaches the endpoint, flashes of pink colour are seen and the titrant is added drop by drop. The endpoint is reached when one drop of titrant turns the mixture a pale pink colour that does not fade.

3. Use the following experimental titration data to calculate the concentration of the acid
being analysed.
Observations:
The initial solution of acetic acid (HC,H,0,) is clear and colourless. A few drops of
phenolphthalein indicator are added to each sample. A dilute solution of sodium hydroxide
(concentration 2.50 x 104 mol/L) is used as the titrant. As the mixture reaches the endpoint,
flashes of pink colour are seen and the titrant is added drop by drop. The endpoint is
reached when one drop of titrant turns the mixture a pale pink colour that does not fade.
Initial burette reading
(mL)
Trial
Volume of acetic acid
Final burette reading (mL)
(HC,Н, О,) (mL)
1
10.00
0.00
24.27
2
10.00
24.27
48.55
10.00
48.55
72.81
Transcribed Image Text:3. Use the following experimental titration data to calculate the concentration of the acid being analysed. Observations: The initial solution of acetic acid (HC,H,0,) is clear and colourless. A few drops of phenolphthalein indicator are added to each sample. A dilute solution of sodium hydroxide (concentration 2.50 x 104 mol/L) is used as the titrant. As the mixture reaches the endpoint, flashes of pink colour are seen and the titrant is added drop by drop. The endpoint is reached when one drop of titrant turns the mixture a pale pink colour that does not fade. Initial burette reading (mL) Trial Volume of acetic acid Final burette reading (mL) (HC,Н, О,) (mL) 1 10.00 0.00 24.27 2 10.00 24.27 48.55 10.00 48.55 72.81
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