Figure 3. Chair Conformations gt A. B. Given the following data regarding Me 1,3-diaxial interactions, what is the energy different between the most stable chair conformation, and the least stable chair conformation? Interaction 1,3 diaxial strain-Me 1,3 diaxial strain-tBu a. 8.5 kcal/mol b. 1.1 kcal/mol c. 6.7 kcal/mol d. 3.1 kcal/mol Energy different between eq and axial +1.8 kcal/mol +4.9 kcal/mol

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry
Section4.3: Stability Of Cycloalkanes: Ring Strain
Problem 8P: Each H↔H eclipsing interaction in ethane costs about 4.0 kJ/mol. How many such interactions are...
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Figure 3. Chair Conformations
Dt
A.
B.
Given the following data regarding Me 1,3-diaxial interactions, what is the energy different between
the most stable chair conformation, and the least stable chair conformation?
Interaction
1,3 diaxial strain-Me
1,3 diaxial strain-tBu
a. 8.5 kcal/mol
b.
1.1 kcal/mol
c. 6.7 kcal/mol
d. 3.1 kcal/mol
Energy different between eq and axial
+1.8 kcal/mol
+4.9 kcal/mol
Transcribed Image Text:Figure 3. Chair Conformations Dt A. B. Given the following data regarding Me 1,3-diaxial interactions, what is the energy different between the most stable chair conformation, and the least stable chair conformation? Interaction 1,3 diaxial strain-Me 1,3 diaxial strain-tBu a. 8.5 kcal/mol b. 1.1 kcal/mol c. 6.7 kcal/mol d. 3.1 kcal/mol Energy different between eq and axial +1.8 kcal/mol +4.9 kcal/mol
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