Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 9.5, Problem 14P
What product will be obtained from the reaction of each of the following alcohols with HOCL?
a. 3-pentanol
b. 2-methyl-2-pentanol
c. 1-petanol
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7
Give the IUPAC name for the following compound.
OH
A. 3-methyl-1-pentenyl alcohol B. 3-vinyl-1-butanol
C. 3-methyl-4-penten-1-ol
CHOOSE THE LETTER OF THE CORRECT ANSWER IN EACH NUMBER.
1. The delighted odor of melted butter is attributed to this four-carbon dione. What could be the IUPAC NAME of this ketone?
a. Butanone
b. Pentanedione
c. Hexanone
d. Butanedione
2. Carbocation stability is important in reaction mechanisms involving alcohols. Based on the general structure of alcohols, rank the carbocation stability of alcohols (increasing trend) if a central carbon is the point of reference.
a. Tertiary alcohol > Primary alcohol > Secondary alcohol
b. Primary alcohol > Secondary alcohol > Tertiary alcohol
c. Secondary alcohol > Tertiary alcohol > Primary alcohol
d. Tertiary alcohol > Secondary alcohol > Primary alcohol
3. Which type of alcohol generally exhibits a higher dipole moment relative to linear alcohol?
a. Cyclic alkyl alcohol
b. Allylic alcohol
c.Tertiary alcohol
d. Secondary alcohol
What is produced when methanal
undergoes Grignard reaction?
O A. primary alcohol
B. secondary alcohol
O C. tertiary alcohol
O D. no reaction
Chapter 9 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 9.1 - Draw the structures of straight-chain alcohols...Ch. 9.1 - Prob. 2PCh. 9.1 - Prob. 3PCh. 9.2 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 9.2 - Prob. 5PCh. 9.2 - The observed relative reactivities of primary,...Ch. 9.4 - Which of the following alcohols would dehydrate...Ch. 9.4 - Prob. 10PCh. 9.4 - Prob. 11PCh. 9.4 - Prob. 12P
Ch. 9.4 - Prob. 13PCh. 9.5 - What product will be obtained from the reaction of...Ch. 9.5 - Prob. 15PCh. 9.6 - a. What is each ethers systematic name? 1....Ch. 9.8 - Draw the structure of the following: a....Ch. 9.8 - Prob. 20PCh. 9.8 - Would you expect the reactivity of a five-membered...Ch. 9.9 - Explain why the two arene oxides in Problem 22...Ch. 9.9 - Which compound is more likely to be...Ch. 9.11 - The following three nitrogen mustards were studied...Ch. 9 - What are the common and systematic names of the...Ch. 9 - Prob. 28PCh. 9 - Prob. 29PCh. 9 - Prob. 30PCh. 9 - Prob. 31PCh. 9 - What is the major product obtained from the...Ch. 9 - Draw structures for the following: a....Ch. 9 - Prob. 34PCh. 9 - Prob. 35PCh. 9 - Prob. 36PCh. 9 - Prob. 37PCh. 9 - Ethylene oxide reacts readily with HO.because of...Ch. 9 - Propose a mechanism for each of the following...Ch. 9 - Which of the following ethers would be obtained in...Ch. 9 - Show how each of the following syntheses could be...Ch. 9 - Prob. 42PCh. 9 - Prob. 43PCh. 9 - Prob. 44PCh. 9 - Propose a mechanism for each of the following...Ch. 9 - a. Propose a mechanism for the following reaction:...Ch. 9 - Three arene oxides can be obtained from...Ch. 9 - Prob. 48PCh. 9 - The following reaction takes place several times...Ch. 9 - Show how each of the following compounds could be...Ch. 9 - Propose a mechanism for the following reaction:Ch. 9 - Propose a mechanism for the following reaction:Ch. 9 - What alkenes would you expect to be obtained from...Ch. 9 - Triethylenemelamine (TEM) is an antitumor agent....Ch. 9 - When a diol that has OH groups on adjacent carbons...Ch. 9 - What product is obtained when...Ch. 9 - Prob. 58P
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