Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 8, Problem 8.42P
On the basis of VSEPR, predict the structures of
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7.
Please draw the structure of cis-[COB14C12]° and determine its point group.
Draw the Lewis structure of SF4, determine its molecular geometry and point group, you will find that
the molecule is:
O Polar but not chiral
Non-polar but chiral
Polar and chiral
O Non-polar and not chiral
5. (a) Deduce the point group of the follo
species :
OH
(i)
HO
HO,
(ü) Co4(Cp)4
(iüi) PF3CI2 (one Cl axial and
one Cl equatorial)
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Inorganic Chemistry
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- Determine the point group of the following. Consider all square planar PtCl4²- Pt(CO)Cl3 cis-Pt(CO)2Cl2 trans-Pt(CO)2Cl2arrow_forward(a) What does the term diamagnetism mean? (b) How doesa diamagnetic substance respond to a magnetic field?(c) Which of the following ions would you expect to bediamagnetic: N22 -, O22 -, Be22 + , C2-?arrow_forwardwhy doesn't F22+ occur (with respect to molecular orbital theory)? illustrate as needed.arrow_forward
- What is the main difference between space group and point group symmetries? Which one do we prefer in explaining the physical properties?arrow_forward8. (a) Define chrömophore. Classify according to the type of electronic transitions, giving examples. the chromophoresarrow_forwardChemistry How many possible isomers are there of the ion IO2F32-? Sketch these, and indicate the point group of each.arrow_forward
- E10A.5(b) Assign the following molecules to point groups: (i) HF (ii) IF, (pentagonal bipyramid), (iii) CIF, (T-shaped), (iv) Fe,(CO), (3), (v) cubane, C,H, (vi) tetrafluorocubane, C,H̟F, (4). HO co Fe co F 3 4arrow_forwardSketch the molecular orbital energy level diagram for XeF and deduce its ground-state electron configuration. Is XeF likely to have a shorter bond length than XeF+?arrow_forwardPredict the electron-domain and molecular geometries of (a) BrF3 (b) SF5 + Illustrate how you arrived at your answer.arrow_forward
- Provide possible molecular structures for NbF5 with C4v and D3h point groupsarrow_forward2. For the following molecules, name the idealized VSEPR geometry and assign the point group: (a) GeH₂D₂ (D = deuterium, is distinguishable from hydrogen); (b) AsF5; (c) C₂H₂; (d) [BrF4]; (e) SO₂Cl2.arrow_forward(b) In the construction of the molecular orbital diagram of a polyatomic molecule (SF6), 12 valence electrons are used to occupy 10 MO; account for the origin of the 12 electrons and the 10 MOsarrow_forward
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