Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 6.8, Problem 19P

Consider the following energy diagram.

Chapter 6.8, Problem 19P, Problem 6.19 Consider the following energy diagram.

How many steps are involved in this

(a) How many steps are involved in this reaction?

(b) Label Δ H ° and E a for each step, and label Δ H ° overall .

(c) Label each transition state.

(d) Which point on the graph corresponds to a reactive intermediate?

(e) Which step is rate-determining?

(f) Is the overall reaction endothermic or exothermic?

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For the reaction ABC + D⇌ AB +CD, ΔHrxn°=-55 kJ/mol and Ea(fwd)=215 kJ/mol. Assuming a one-stepreaction, (a) draw a reaction energy diagram; (b) calculate Ea(rev);and (c) sketch a possible transition state if ABC is V-shaped.step, (a) draw a reaction energy diagram; (b) calculate ΔHrxn°;and (c) sketch a possible transition state
1. If the PE of the reactants is 430kJ and the PE of the products is 190kJ. What is the ΔH? ... 2. If the PE of the reactants is 430kJ and the activation energy is 220, how much TOTAL energy will be needed to be added for the reaction to proceed?
(a) Select all of the correct statements about reaction rates from the choices below. The lower the rate of a reaction the longer it takes to reach completion.Reaction rates increase with increasing temperature.The slowest step in a reaction is called the rate-determining step.Catalysts increase reaction rates.The fastest step in a reaction is called the rate-determining step.As a reaction progresses its rate goes down.Reaction rates can show little change as masses of solid reactants increase.

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Organic Chemistry (6th Edition)

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