Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27.5, Problem 8P
Rank the following groups of monomers from most able to least able to undergo anionic
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Chapter 27 Solutions
Organic Chemistry (8th Edition)
Ch. 27.3 - Prob. 1PCh. 27.3 - Prob. 2PCh. 27.3 - Prob. 3PCh. 27.3 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.4 - Prob. 7PCh. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P
Ch. 27.6 - Explain why, when propylene oxide undergoes...Ch. 27.6 - Which monomer and which type of initiator can you...Ch. 27.6 - Prob. 13PCh. 27.8 - Draw a short segment of gutta-percha.Ch. 27.8 - Prob. 15PCh. 27.11 - Prob. 16PCh. 27.11 - Write an equation that explains what happens if a...Ch. 27.11 - What happens to polyester slacks if aqueous NaOH...Ch. 27.11 - a. Propose a mechanism for the formation of the...Ch. 27.11 - Explain why, when a small amount of glycerol is...Ch. 27.12 - Propose a mechanism for the formation of melmac.Ch. 27.12 - Prob. 22PCh. 27.13 - Prob. 23PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 37PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 39PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 45PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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- Draw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.arrow_forwardA3 Anionic polymerization of styrene is generally known to produce polymers with a narrow molecular weight distribution. Explain the reason for this.arrow_forwardExplain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forward
- 4.2) Draw the structure of the polymer produced in the following reaction. H₂N NH₂ Karrow_forwardWhat product is obtained from ring-opening metathesis polymerization of each of the following compounds? (Hint: In each case, the product is an unsaturated hydrocarbon with a high molecular weight.)arrow_forward(CH2) (CH) One or more of the monomers below are needed to make the polymer Choose which one(s). но- (CH2)4 O NH2-(CH2)6–NH2 CI O H H. CNarrow_forward
- Draw a pair of compounds that would react to give the polymer shownarrow_forwardNH2 Dry-erase boards, or whiteboards, in classrooms consist of a network polymer similar to Bakelite that is made from formaldehyde and melamine. (a) Propose a structure for the polymer formed. (b) Why is this type of polymer suitable for use in whiteboards? 'N. H2N `NH2 Melaminearrow_forwardWhich reaction—dehydration synthesis or hydrolysis—converts a polymer to its monomers? Which one convertsmonomers to a polymer? Explain your answerarrow_forward
- (d) Another variation on this type of polymer is used in hair gels. In these, the polymer chains are cross-linked by a compound known as pentaerythritol. но- OH но- OH pentaerythritol ( By what type of chemicat reaction are the cross-links in this polymer formed? (i) it is important that the gel should be easily washed out of hair What is it about the structure of the polymer that allows this to happen?arrow_forward1. which cannot be obtained by radical polymerization of its vinyl monomer Poly(ethylene) obtained by polymerization of ethylene monomer Poly(propylene) obtained by polymerization of propylene monomer Poly(vinyl chloride) obtained by polymerization of vinyl chloride monomer Poly(acrylonitrile) obtained by polymerization of acrylonitrile monomerarrow_forward(CH2 (CH₂ n One or more of the monomers below are needed to make the polymer Choose which one(s). OH H H H H CH HO-(CH2)4--OH ONH2 H -(CH2)6-NH2 X H CIarrow_forward
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