Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 21.9, Problem 6P

If methionine is always the first amino acid incorporated into an oligopeptide, what oligopeptide is coded for by the following stretch of mRNA?

5’—G—C—A—U—G—G—A—C—C—C—C—G—U—U—A—U—U—A—A—A—C—A—C—3’

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The amino acid histidine has ionizable groups with pK₁ values of 1.8, 6.0, and 9.2, as shown. COOH H¸Ñ—CH CH₂ H 2 CH pH = COO™ H¸Ñ—CH 1.8 pk₁ CH₂ H lonizable -COOH = -COO- group CH COO™ H₂N-CH 6.0 pK₂2 CH₂ H -HisH -His N CH COO™ H₂N-CH 9.2 pk CH₂ H 2 —NH — —NH, CH A biochemist makes up 95 mL of a 0.13 M solution of histidine at a pH of 5.3. She then adds 60 mL of 0.10 M HCl. What is the pH of the resulting solution?
If methionine is always the first amino acid incorporated into an oligopeptide, what oligopeptide is coded for by the following stretch of mRNA? 5′-G-C-A-U-G-G-A-C-C-C-C-G-U-U-A-U-U-A-A-A-C-A-C-3′
Researchers analysed a glycopeptide (a peptide carrying one or several oligosaccharide groups) and determined both the sequence of the peptide and the sequence of the sugar molecule. The latter was identified as a diholoside coupled to the peptide by an osidic bond. The systematic name of this sugar is: B-D-glucopyranosyl-(1→4)-ß-D-galactopyranose. : Represent the chemical formula of this diholoside in a way that all oses are Question 1 represented according to the Haworth convention. Apart from the furane and/or pyrane cycles all atoms of this molecule must be given.

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Essential Organic Chemistry (3rd Edition)

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