Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 14.3, Problem 14.4QC
Problem 15-4
3-Amino-2-butanol has two stereocenters (carbons 2 and 3); thus, 22 = 4 stereoisomers are possible for it.
'CHa
H-“C-OH
3I
h2n—c— h 4ch3 ch3 H-C-OH
I
H —C—NH2
ch3 ch3 HO-C-H
I
H — C— NH2
ch3 ch3 HO-C-H
I
H,N—C-H
ch3
- Which stereoisomers are pairs of enantiomers?
- Which sets of stereoisomers are diastereomers?
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Problem Three
a) Tamoxifen is a breast cancer drug.
i) Identify which geometrical isomer it is by assigning a one-letter stereodescriptor:
ii) Predict the acid-base behaviour of Tamoxifen and name its functional groups
b) i) The Parkinson's disease drug Levodopa is shown. Which one-letter
stereodescriptor (S or R) describes its chiral centre?
your
HO.
HO
NH₂
OH
PROBLEM 13-3Determine the number of different kinds of protons in each compound. 1-bromo-2-methylbenzene,
Identify the family to which the compound shown belongs:
H3CO-CH2-CH3
amine
alcohol
aldehyde
ketone
carboxylic acid
ester
ether
Submit
Request Answer
Part C
Identify the family to which the compound shown belongs:
H3C-CH2-C-CH2-CH3
||
alcohol
ether
aldehyde
ketone
carboxylic acid
ester
amine
Submit
Request Answer
O o C
Chapter 14 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 14.1 - Prob. 14.1QCCh. 14.2 - Problem 15-2 Assign priorities to the groups in...Ch. 14.2 - Problem 15-3 Assign an R or S configuration to the...Ch. 14.3 - Problem 15-4 3-Amino-2-butanol has two...Ch. 14.3 - Prob. 14.5QCCh. 14.3 - Prob. 14.6QCCh. 14 - 15-7 Answer true or false. The cis and trans...Ch. 14 - 15-8 What does the term “chiral” mean? Give an...Ch. 14 - 15-9 What does the term “achiral” mean? Give an...Ch. 14 - 15-10 Define the term “stereoisomer.” Name three...
Ch. 14 - 15-11 In what way are constitutional isomers...Ch. 14 - 15-12 Which of the following objects are chiral...Ch. 14 - Prob. 7PCh. 14 - Prob. 8PCh. 14 - Prob. 9PCh. 14 - Prob. 10PCh. 14 - 15-15 Explain why the carbon of a carbonyl group...Ch. 14 - 15-16 Which of the following compounds contain...Ch. 14 - 15-17 Which of the following compounds contain...Ch. 14 - Prob. 14PCh. 14 - 15-19 Draw the mirror image for each molecule: OH...Ch. 14 - Prob. 16PCh. 14 - 15-21 Answer true or false. For a molecule with...Ch. 14 - Prob. 18PCh. 14 - Prob. 19PCh. 14 - Prob. 20PCh. 14 - Prob. 21PCh. 14 - 15-26 For centuries, Chinese herbal medicine has...Ch. 14 - Prob. 23PCh. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Prob. 26PCh. 14 - Prob. 27PCh. 14 - Prob. 28PCh. 14 - Prob. 29PCh. 14 - Prob. 30PCh. 14 - 15-35 Following are structural formulas for three...Ch. 14 - Prob. 32PCh. 14 - 15-37 Consider a cyclohexane ring substituted with...Ch. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Prob. 36PCh. 14 - 15-41 Compound A(C5Hh, is not optically active and...Ch. 14 - Prob. 38PCh. 14 - 15-43 Triamcinolone acetonide, the active...Ch. 14 - 15-44 Consider the structure of the...Ch. 14 - Prob. 41PCh. 14 - 15-46 Consider Lunesta, a nonbenzodiazepine...Ch. 14 - Prob. 43PCh. 14 - Prob. 44P
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