Write TRUE if the underlined word/phrase makes the statement correct. Otherwise, write the correct WORD/PHRASE that will make the statement true. a. 2-phenylacetaldehyde is soluble with concentrated sulfuric acid due to acid-base neutralization. b. 2-phenylacetic acid has a solubility classification of A2, which means it is soluble in 5.O%NaOH and insoluble in 5.O% NaHCO3. c. Scratching the inner sides of the beaker to begin recrystallization is advised for unsaturated solutions.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter11: Ethers, Epoxides, And Sulfides
Section: Chapter Questions
Problem 11.41P: Aldehydes and ketones react with one molecule of an alcohol to form compounds called hemiacetals, in...
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Write TRUE if the underlined word/phrase makes the statement correct. Otherwise, write the correct WORD/PHRASE that will make the statement true.

a. 2-phenylacetaldehyde is soluble with concentrated sulfuric acid due to acid-base neutralization.

b. 2-phenylacetic acid has a solubility classification of A2, which means it is soluble in 5.O%NaOH and insoluble in 5.O% NaHCO3.

c. Scratching the inner sides of the beaker to begin recrystallization is advised for unsaturated solutions.

d. Washing with hot solvent eliminates adhered mother liquor and avoids crystal dissolution.

e. To extract a nonpolar organic compound using solvent extraction, the extracting solvent must be nonpolar, and the washing solvent must be also nonpolar.

f. Addition of 6.0 M NaCl extracts saponins by converting them to their salt form.

g. The stationary phase in the paper chromatography experiment is the filter paper.

h. When the spots have low concentration, they will not be observed as visible spots in the chromatogram.

i. An isomer in anti-staggered conformation has higher potential energy than the isomer in eclipsed conformation.

j. The addition of excess HCl assures that the formation of tert-butyl chloride is favored.

k. If the temperature during distillation of crude tert-butyl chloride reached 90°C, the distillate would contain tert-butyl chloride and di-tert-butyl ether.

l. Addition of KMnO4 to 2,3-dihydroxycyclohexanone results in a purple solution.

m. 2-phenylhexanol will result in the formation of brown precipitate in neutral KMnO4 and homogenous solution in Lucas reagent.

n. A temperature-sensitive substance may be purified using steam distillation.

o. The formation of a sooty flame upon combustion of hydrocarbons indicates complete combustion which means that the sample has a high C to H ratio.

p. Halides make the aromatic ring less electron-rich, and they direct the incoming group at the meta position.

q. The rate-determining step in the mechanism of electrophilic aromatic substitution is the generation of a positively charged intermediate, the σ-complex, when an electrophile forms a bond to the ring.

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Write TRUE if the underlined word/phrase makes the statement correct. Otherwise, write the correct WORD/PHRASE that will make the statement true.

d. Washing with hot solvent eliminates adhered mother liquor and avoids crystal dissolution.

e. To extract a nonpolar organic compound using solvent extraction, the extracting solvent must be nonpolar, and the washing solvent must be also nonpolar.

f. Addition of 6.0 M NaCl extracts saponins by converting them to their salt form.

g. The stationary phase in the paper chromatography experiment is the filter paper.

h. When the spots have low concentration, they will not be observed as visible spots in the chromatogram.

i. An isomer in anti-staggered conformation has higher potential energy than the isomer in eclipsed conformation.

j. The addition of excess HCl assures that the formation of tert-butyl chloride is favored.

k. If the temperature during distillation of crude tert-butyl chloride reached 90°C, the distillate would contain tert-butyl chloride and di-tert-butyl ether.

l. Addition of KMnO4 to 2,3-dihydroxycyclohexanone results in a purple solution.

m. 2-phenylhexanol will result in the formation of brown precipitate in neutral KMnO4 and homogenous solution in Lucas reagent.

n. A temperature-sensitive substance may be purified using steam distillation.

o. The formation of a sooty flame upon combustion of hydrocarbons indicates complete combustion which means that the sample has a high C to H ratio.

p. Halides make the aromatic ring less electron-rich, and they direct the incoming group at the meta position.

q. The rate-determining step in the mechanism of electrophilic aromatic substitution is the generation of a positively charged intermediate, the σ-complex, when an electrophile forms a bond to the ring.

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