Write the structure for the most oxidized organic product when each of the following is reacted with potassium dichro- mate. Write NR if no reaction occurs. (a) methanol (b) ethyl alcohol (c) 2,3,4-trimethyl-2-pentanol (d) 3-hexanol

Write the structure for the most oxidized organic product when each of the following is reacted with potassium dichro- mate. Write NR if no reaction occurs. (a) methanol (b) ethyl alcohol (c) 2,3,4-trimethyl-2-pentanol (d) 3-hexanol

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter22: Organic Chemistry And Biochemistry

Section: Chapter Questions

Problem 52QE

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

2. Write the structure for the most oxidized organic product when each of the following is reacted with potassium dichro- mate. Write NR if no reaction occurs.
(a) methanol
(b) ethyl alcohol
(c) 2,3,4-trimethyl-2-pentanol
(d) 3-hexanol

3. Alcohols can be made by reacting alkyl halides with sodium hydroxide as follows:
RX +. NaOH ROH + NaX

Give the names and formulas of the alcohols produced from the following alkyl bromides by this method:
(a) 2-bromobutane
(b) 2-bromo-3-ethylpentane
(c) bromocyclopentane

Definition Definition Organic compounds in which one or more hydrogen atom in an alkane is replaced by a halogen atom (fluorine, chlorine, bromine, or iodine). These are also known as haloalkanes.

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