wing pairs of molecules, which one has the molecule with the higher boiling point listed second?  Need full solutions

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter11: Alkanes
Section: Chapter Questions
Problem 11.47P
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For the following pairs of molecules, which one has the molecule with the higher boiling point listed second?  Need full solutions

   

CH2F2 and CF4

   

CH3CH3 and CH3OH

   

HOCH2CH2CH2OH and CH2CH2CH2OH

   

CH3CH2CH3 and CH3CH3

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