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Why the most densely packed (110) surface is least active and the open (111) plane exhibits the
highest sticking coefficient?
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- If concentration of [CrO4 ] in Expt. 7 is found to be 6.7 x 105 M, what is the experimental Ksp of Ag,CrO4? a) 3.0 x 1013 b) 6.0 x 1013 c) 1.2 x 1012 d) 1.8 x 108 Ksp of Ag.CrO4 = [Ag]° [CrO,?] Ag,CrO4 2 Ag+(aq) + CrO,-(aq), moles, and concentration, of Ag+ are twice those of Cro Ksp of Ag.CrO, = [Ag"] [CrO,] = [2Cro.1°[CrO,] = [CrO.,*]What is the electron transfer of Fe2O3+C=CO2+Fe?. A student collects the following data for the absorbance of a complex measured in 1.00 cmspectrophotometric cells. The molar absorptivity (ε) of the complex under investigation is 2.25×103L/mol·cm. Calculate the concentration of the complex in solution at each time of the reaction.Time (min)MeasuredAbsorbanceComplex Concentration(M)0.000 1.50010.000 1.31320.000 1.12530.000 0.93840.000 0.750
- Cr(s) salt bridge -Zn(s) 2.50 M 0.20 M Zn(NO3)2 Cr(NO3)3 Cr³+ (aq) + 3e →Cr (s) Eºred= - 0,740 V Zn²+ (aq) + 2e → Zn (s) Eºred= - 0,763 V R = 8,314 J mol-¹ K-1 dan = 9,650* 104 J/Volt mol e Under standard conditions (250 C, 1.0 atm): i. If Cr metal is immersed in a solution of Zn(NO3)2, will the Cr metal be/can be oxidized? ii. Calculate the standard cell potential (in V) at 250C for a Galvanic cell prepared with a Cr electrode in a Cr(NO3)3 solution and a Zn electrode in a Zn(NO3)2 solution. iii. Write the reaction and the cell notation jv. Calculate the equilibrium constantGive the formula of each of the following coordination entities :(i) Co3+ ion is bound to one Cl–, one NH3 molecule and two bidentate ethylene diamine (en) molecules.(ii) Ni2+ ion is bound to two water molecules and two oxalate ions.Write the name and magnetic behaviour of each of the above coordination entities.(At nos. Co = 27, Ni = 28)2. The following table gives the values of the preferential adsorption (Qe) and respective equilibrium concentrations of the bulk solution (Ce) obtained during the measurement of adsorption of acetic acid from an aqueous solution on the charcoal: Ce (mol/L) Qe (mol/g-charcoal) 4.660 x 104 0.0181 0.8827 2.479 x 103 If you know that water is not adsorbed on the charcoal and that adsorption can be described by the Freundlich isotherm, calculate (a) both constants of Freundlich equation (b) mole amount of the acetic acid removed from 400 cm³ of solution by adsorption on 50 g ofcharcoal, if the concentration of equilibrium bulk solution was found to be 0.3 mol dm-³.
- 3516S → ? + 0-1e ? → 9039Y + 0-1e 21083Bi → ? + 42He ? → 13559Pr + 0+1e Match from the following : P , Nd, Ce, Cl, Sr, Ti, At, ZrCalculate the rate constant k1, for the below outer-sphere electron transfer reaction: [Fe(CN)6]*- + Ce* → [Fe(CN),]* + Ce** E° = -0.76 V, T = 300 K, log f= -2.33 The relevant self-exchange rate constants are: k11 = 7.4 x 102 M' s'! ky = 4.4 M' s! [Fe(CN)6]+3- Cet3+ Explain why one can isolate the A and A isomers for [Co(en)3]3* but not for [Fe(en);]*.K2Cr2O7 + 7H2C2O4·2H2O → 2K(Cr(C2O4)2(H2O)2) + 6CO2 + 17H2O Calculate theoretical yield of: K[Cr(C204)2(H20)2] · 2H2O (3 g of oxalic acid dihydrate (H2C2O4·2H2O) )(1 g of potassium dichromate (K2Cr2O7) )(20 mL of 95% ethanol)
- What is the main origin of difference in the magnetic properties of lanthanides and transition elements?Calculate the mass of copper (I) sulfide that will completely dissolve in 1.0 L of water. The Ksp of Cu₂S is 6.0 x 10-³7.Calculate the Ksp for the slightly soluble salt Ce(IO3)4, if at equlibrium, the salt has measured concentration shown: [Ce4+] = 1.8 x 10-4 M [IO3-] = 2.6 x 10-13 M