Why is there an overall contraction in ionic radii? Why is radius of Ti^ 2+ less than theoretical value? Why is the radius of Cr^ 2+ larger than that of V^ 2+.

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter2: Atomic Structure And Periodicity
Section: Chapter Questions
Problem 170CP: We expect the atomic radius to increase going down a group in the periodic table. Can you suggest...
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Ionic radii
 
Why is there an overall contraction in ionic radii? Why is radius of Ti^ 2+ less than theoretical value?
Why is the radius of Cr^ 2+ larger than that of V^ 2+.  
1) Ionic radii – Why is there an overall contraction in ionic
radii? Why is radius of Ti?* less than theoretical value?
110-
Ca2+
100
90
Mn2+
V2+ Cr2+
Fe2+
Co2
Zn2+
70
Cu+
60
Increasing atomic number
1) Ionic radii (cont.) Why is the radius of Cr2+ larger than that
of V2+?
110
Ca?+
100
90
Mn2+
Fe2
Zn+
70
Co2
Cu
N2+
60
Increasing atomic number -
lonic radius (pm)
(wd) snipei Djuoj
Transcribed Image Text:1) Ionic radii – Why is there an overall contraction in ionic radii? Why is radius of Ti?* less than theoretical value? 110- Ca2+ 100 90 Mn2+ V2+ Cr2+ Fe2+ Co2 Zn2+ 70 Cu+ 60 Increasing atomic number 1) Ionic radii (cont.) Why is the radius of Cr2+ larger than that of V2+? 110 Ca?+ 100 90 Mn2+ Fe2 Zn+ 70 Co2 Cu N2+ 60 Increasing atomic number - lonic radius (pm) (wd) snipei Djuoj
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