When the alkyl bromides (listed here) were subjected to hydrolysis in a mixture of ethanol and water (80% EtOH/20% H20) at 55°C, the rates of the reaction showed the following order: (CH3)3CB > CH3B > CH3CH2Br > (CH3)2CHBR Provide an explanation for this order of reactivity. Two different mechanisms are involved. (CH3)3CBr reacts by an * mechanism and apparently this reaction takes place faster. The other three alkyl halides react by * mechanism, and their reactions are slower because the 3. The reaction rates of CH3BR, CH3CH2Br, (CH3)2CHBR are affected by an * and thus their order of reactivity is CH3B > CH3CH2B > (CH3)2CHBR.
When the alkyl bromides (listed here) were subjected to hydrolysis in a mixture of ethanol and water (80% EtOH/20% H20) at 55°C, the rates of the reaction showed the following order: (CH3)3CB > CH3B > CH3CH2Br > (CH3)2CHBR Provide an explanation for this order of reactivity. Two different mechanisms are involved. (CH3)3CBr reacts by an * mechanism and apparently this reaction takes place faster. The other three alkyl halides react by * mechanism, and their reactions are slower because the 3. The reaction rates of CH3BR, CH3CH2Br, (CH3)2CHBR are affected by an * and thus their order of reactivity is CH3B > CH3CH2B > (CH3)2CHBR.
Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions
Section19.SE: Something Extra
Problem 36MP: It is not uncommon for organic chemists to prepare acetals by an exchange-type process known as...
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