What is the reaction mechanism? Scheme 30. Intermolecular Diastereoselective Allylic Ammonium Ylide Generation and [2,3]-Rearrangement Ph Ph Rh2(OAc)4 (0.5 mol%) C6H6, A EtO EtO 125 (5 eq) 20 126 59% 75:25 dr

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
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Problem 20.27P
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What is the reaction mechanism?
Scheme 30. Intermolecular Diastereoselective Allylic
Ammonium Ylide Generation and [2,3]-Rearrangement
Ph
Ph
Rh2(OAc)4 (0.5 mol%)
CeH6, A
EtO
EtO
125 (5 eq)
20
126
59%
75:25 dr
Transcribed Image Text:What is the reaction mechanism? Scheme 30. Intermolecular Diastereoselective Allylic Ammonium Ylide Generation and [2,3]-Rearrangement Ph Ph Rh2(OAc)4 (0.5 mol%) CeH6, A EtO EtO 125 (5 eq) 20 126 59% 75:25 dr
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