what is the of T/K in table? and how can i get 1/T?

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.59P
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what is the of T/K in table?

and how can i get 1/T?

 

3)
For the elementary gas phase reaction H + C₂H4 -> C₂H5, the second-order rate constant, k,
varies with temperature in the following way:
(i)
(ii)
1/T
0.0050
0.0033
T/K
10¹2 k/cm³ molecule¹¹ s-¹
Use all the data to calculate the activation energy and the pre-exponential factor.
Using collision theory, determine a value for the reaction cross-section at 400 K.
EA
k = A e RT
k
0.20 × 1012
1.13 × 1012
198 298 400 511 604
0.20 1.13 2.83 4.27 7.68
Ink = InA -
Ink
26.02
27.75
In k
EA 1
X
R
30.5
29.5
28.5
T
Ink
Temperature dependent reaction rate
..........
Intercept In A
slope = -Ea / R
In k = In A - Ea/RT
1/T (k-¹)
-EA/R = -1074.8 K
EA = 1074.8 K × 8.31 J K-¹ mo
Transcribed Image Text:3) For the elementary gas phase reaction H + C₂H4 -> C₂H5, the second-order rate constant, k, varies with temperature in the following way: (i) (ii) 1/T 0.0050 0.0033 T/K 10¹2 k/cm³ molecule¹¹ s-¹ Use all the data to calculate the activation energy and the pre-exponential factor. Using collision theory, determine a value for the reaction cross-section at 400 K. EA k = A e RT k 0.20 × 1012 1.13 × 1012 198 298 400 511 604 0.20 1.13 2.83 4.27 7.68 Ink = InA - Ink 26.02 27.75 In k EA 1 X R 30.5 29.5 28.5 T Ink Temperature dependent reaction rate .......... Intercept In A slope = -Ea / R In k = In A - Ea/RT 1/T (k-¹) -EA/R = -1074.8 K EA = 1074.8 K × 8.31 J K-¹ mo
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