Answered: (vi) Nitrobenzene is reduced with…

(vi) Nitrobenzene is reduced with Zn/HCl to an amine which is further treated with a mixture of KNO2 and HCl and then the resulting product is boiled with nitrobenzene

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter15: An Introduction To Organometallic Compounds

Section: Chapter Questions

Problem 15.11P

See similar textbooks

Related questions

Q: 4. Write the principal products of the reactions of the following compound with excess of the…

Q: 7. Compound EE, C4H3O shows a positive result (formation of yellow precipitate) when reacted with…

A: Answer:- this question is answered by using the simple concept of chemical reactions of organic…

Q: When a dilute solution of acetaldehyde in D2O containing NaOD is shaken, explain why the methyl…

A: The reason why methyl hydrogens are exchanged with deuterium but the hydrogen attached to the…

Q: When pent-2-yne reacts with mercuric sulfate in dilute sulfuric acid, the product is amixture of two…

Q: Electrophilic nitration of benzoic acid gives almost exclusively 3-nitrobenzoic acid. By drawing the…

A: benzoic acid undergoes electrophilic substitution reaction when reacted with Nitration mixture(1:1…

Q: 3) Isoerythrogenic acid, C18H2602, is an acetylic fatty acid that turns a vivid blue on exposure to…

A: Based on the data given in above question, we can draw the line structure as below- This is also…

Q: In preparation of p-Nitroaniline, Starting material is 50g of p-nitroacetanilide, 22ml of HCI,…

A: A numerical problem based on quantitative analysis, which is to be accomplished.

Q: SN1 substitution and E1 elimination frequently compete in the same reaction.(a) Propose a mechanism…

A: The formation of carbocation is as follows, The formation of carbocation is due to removal of…

Q: Give a rearrangement reaction equation to synthesize N-ethyl-2-methyl-buthylamide from the…

Q: Which of the following statements is correct? A) The haloform reaction proceeds under very…

A: Haloform test is test that is used determine presence of carbonyl compounds containing R-CO-CH3 or…

Q: from acetone and acetoacetic ester and any other reagents NME2 from HO (b) (a) HO. from benzene and…

A: Substitution reaction is the reaction where one group is substituted with another group.…

Q: When pyrrole is added to a dilute solution of D2SO4 in D2O, 2-deuteriopyrrole is formed. Propose a…

A: The mechanism for the formation of 2-deuteriopyrrole has to be given,

Q: The ketone shown was prepared in a three-step sequence from ethyl trifluoroacetate. The first step…

A: Ethyl Trifluoroacetate on reaction with NH3 give amide. Amides on reaction with Grignard reagent…

Q: ) Compound AA has a molecular formula of CsHso and gives a positive result using Tollen's reagent.…

Q: The reaction of sodium borohydride with ketones proceeds rapidly at room temperature, forming an…

A: A structural formula consists of symbols for the atoms that are connected by lines which represents…

Q: Compelling evidence for the existence of a tetrahedral intermediate in nucleophilic acyl…

A: The first step of ester hydrolysis under alkaline condition is the formation Td intermediate. This…

Q: Which of the following statements is correct? A. The haloform reaction proceeds under very difficult…

Q: Represent the reaction mechanism of the alkene supplied to you with propanol in the presence of…

A: Alkene reacts with alcohol in presence of an acid catalyst by electrophilic addition reaction…

Q: Propose a mechanism for both parts of the Wolff–Kishner reduction of cyclohexanone: the formation of…

A: The reduction of aldehydes and ketones to alkanes by reaction of corresponding aldehyde and ketone…

Q: The reaction of sodium borohydride with ketones proceeds rapidly at room temperature, forming an…

Q: constriction of bronchial tubes. Cromolyn sodium is synthesized in the above series of steps. 1.…

A: In any reaction bond making and breaking takes place and move ment of electron is found .

Q: Compelling evidence for the existence of a tetrahedral intermediate in nucleophilic acyl…

A: Considering the two reaction mechanism pathways-

Q: Electrophilic nitration of benzoic acid gives almost exclusively 3-nitrobenzoic acid. By drawing the…

A: An aromatic acid called benzoic acid is amenable to common electrophilic benzene ring replacement…

Q: Complete the table by drawing the sulfonamides produced, if any, upon the addition of BSC and excess…

A: ✓About to BSC- Benzene sulphonyl chloride is abbreviated as BSC.It is a chemical reagent called…

Q: Compelling evidence for the existence of a tetrahedral intermediate in nucleophilic acyl…

A: Considering the two reaction mechanism pathways-

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: Retrosynthesis analysis gives (2) and (3).

Q: Give a plausible mechanism for the reaction of o-bromobenzoic acid and 1-propanol (with HCI) to…

Q: In preparation of p-Nitroaniline, Starting material is 50g of p-nitroacetanilide, 22ml of HCI, 20g…

A: Given: mass of p-nitroacetanilide used = 50 g Mass of p-nitroaniline obtained = 20 g

Q: Propose the structures for hydrocarbons (and give the organic reaction) that give the following…

Q: When N-bromosuccinimide is added to hex-1-ene in CCl4 and a sunlamp is shone on themixture, three…

A: NBS is a source of bromine atom which abstract hydrogen atom from alkene at allylic position and…

Q: An unknown organic compound P has a molecular formula of CaH160. P reacts with 2,4-…

A: Given , unknown organic compoun P has molecular formula C8H16O P react with dinitrophenylhydrazine…

Q: The structure below represents a tetrahedral alkoxide-ion intermediate formed by addition of a…

A: The starting acid derivative and the ultimate carboxylic acid derivative product is drawn in the…

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: There are four chiral centres in the estrone that are marked in the structure below,

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: The stereo selective double Heck reaction of arene (1) is highly efficient strategy to prepare the…

Q: Vanillin, NaI/NaOCL, ethanol/H2O, bleach are reacted in an electrophilic aromatic substitution…

A: NaOCl (Sodium hypochlorite) oxidises the NaI to gives I2 molecule, a source of iodonium ion. In…

Q: Give the products expected when acetic formic anhydride reacts with (i) aniline and(ii) benzyl…

A: The mechanism for the reaction between acetic formic anhydride and aniline is as follows

Q: The following is the strategy in modern synthesis of indigo dye in industry. A, formaldehyde and…

A: see below

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: Compound (2) has the aromatic ring that becomes ring A of estrone. Compound (3) has fused six and…

Q: Isoerythrogenic acid, C18H26O2, is an acetylic fatty acid that turns a vivid blue on exposure to UV…

A: Based on the data given above, the line structure is shown below- It is also known as isanic acid.

Q: a) Provide reagents, reaction conditions and a curly arrow mechanism for the three component…

Q: O2N 02 N H2 S04

A: The given compound get rearranged in the presence of an acid catalyst. The compound contains a…

Q: Compound EE, C4H8O shows a positive result (formation of yellow precipitate) when reacted with…

A: This is a question from inorganic reaction.

Q: The structural formulae of wWo compounds X and Y are given below: OCH(CH,)2 Y a) Write a reaction…

A: The question is based on the concept of organic reactions. we have to convert one compound into…

Q: Compound EE, C5H10O gives a positive result (formation of silver mirror) when reacted with Tollen’s…

Q: 3. Benzalacetophenone can be nitrated to give the mononitro derivative. (a) Provide the structure of…

A: A question based on aromaticity that is to be accomplished.

Q: R OH 1. NaH MOTS PCI; Mg/dietil éter, H,O

Q: Compelling evidence for the existence of a tetrahedral intermediate innucleophilic acyl substitution…

A: In nucleophilic acyl substitution reaction, the nucleophile gets into position of leaving group.

Concept explainers

Ionic Equilibrium

Chemical equilibrium and ionic equilibrium are two major concepts in chemistry. Ionic equilibrium deals with the equilibrium involved in an ionization process while chemical equilibrium deals with the equilibrium during a chemical change. Ionic equilibrium is established between the ions and unionized species in a system. Understanding the concept of ionic equilibrium is very important to answer the questions related to certain chemical reactions in chemistry.

Arrhenius Acid

Arrhenius acid act as a good electrolyte as it dissociates to its respective ions in the aqueous solutions. Keeping it similar to the general acid properties, Arrhenius acid also neutralizes bases and turns litmus paper into red.

Bronsted Lowry Base In Inorganic Chemistry

Bronsted-Lowry base in inorganic chemistry is any chemical substance that can accept a proton from the other chemical substance it is reacting with.

Question

What happens when (write the reactions involved)

(vi) Nitrobenzene is reduced with Zn/HCl to an amine which is further treated with a mixture of
KNO2 and HCl and then the resulting product is boiled with nitrobenzene

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Isoerythrogenic acid, C18H26O2, is an acetylic fatty acid that turns a vivid blue on exposure to UV light. On Catalytic hydrogenation over a palladium catalyst, five molar equivalents of hydrogen are absorbed, and stearic acid, CH3(CH2)16CO2H, is produced. Ozonolysis of isoerythrogenic acid yields the following products: formaldehyde, CH2O, malonic acid, HO2CCH2CO2H, adipic acid, HO2C(CH2)4CO2H, and the aldehyde carboxylic acid, OHC(CH2)6CO2H. Provide a structure for isoerythrogenic acid.
Predict the products of the reactions of the following compounds with:(1) chromic acid or excess sodium hypochlorite with acetic acid.(2) PCC or NaOCl (1 equivalent) with TEMPO.(a) cyclohexanol (b) 1-methylcyclohexanol
The base-promoted rearrangement of an -haloketone to a carboxylic acid, known as the Favorskii rearrangement, is illustrated by the conversion of 2-chlorocyclohexanone to cyclopentanecarboxylic acid. It is proposed that NaOH first converts the a-haloketone to the substituted cyclopropanone shown in brackets and then to the sodium salt of cyclopentanecarboxylic acid. (a) Propose a mechanism for base-promoted conversion of 2-chlorocyclohexanone to the proposed intermediate. (b) Propose a mechanism for base-promoted conversion of the proposed intermediate to sodium cyclopentanecarboxylate.
Phenols are less acidic than carboxylic acids, with values of pKa around 10. Phenols aredeprotonated by (and therefore soluble in) solutions of sodium hydroxide but not by solutions of sodium bicarbonate. Explain how you would use extractions to isolate the three purecompounds from a mixture of p-cresol (p-methylphenol), cyclohexanone, and benzoic acid.
Compound EE, C4H8O shows a positive result (formation of yellow precipitate) when reacted with lodoform reagent. Reduction of compound EE with sodium boron hydride, NABH4 followed by acidified water, H3O* produces an alcohol FF. Compound FF is treated with phosporus pentachloride, PCI5 to form compound GG. Prolong heating of compound EE with concentrated solution of acidified potassium permanganate, KMNO4 will form compound HH and II. Sebatian EE, C4H8O menunjukkan keputusan positif (pembentukkan mendakan kuning) apabila bertindak balas dengan reagen lodoform. Penurunan sebatian EE dengan natrium boron hidrida, NaBH4 diikuti dengan air berasid, H30* menghasilkan satu alkohol FF. Sebatian FF telah dirawat dengan fosforus pentaklorida, PCI5 untuk membentuk sebatian GG. Pemanasan yang berterusan bagi sebatian EE dengan larutan pekat kalium permanganat, KMNO4 berasid akan membentuk sebatian HH dan II. Draw the structural formula of EE, FF, GG, HH and II. Lukiskan formula struktur bagi EE,…
A task is assigned to an undergraduate student to test two samples (known as compounds K and L) in the laboratory. She placed these two compounds through various scientific tests. She discovered that these compounds have the same molecular formula, CSHSO. When treated with 2,4-dinitrophenylhydrazine, all of these compounds produce brightly coloured precipitate, and both are reduced to an organic compound with the molecular formula C§H100. However, compound K can be easily oxidized by chromic acid to formed compound N and vice versa for compound L. Furthermore, when both compounds react with Fehling's solutions, they produce negative results. However, only compound K forms a silver mirror when it reacts with Tollen's reagent, and compound L does not. Identify the possible structural formulae for compounds K, L, and N by ignoring their position isomerism. Indicate the formation of compound N from compound K. Predict the chemical reaction that occurs when compound L reacts with 2,4-…
(b) Compound AA has a molecular formula of CsH&O and gives a positive result using Tollen's reagent. The reaction of compound AA with hot acidified potassium permanganate, KMNO4 gives compound BB. The catalytic hydrogenation of compound AA with nickel, Ni produced compound Cc. The reaction of compound BB with ethanamine, CH:CH2NH2 produces compound DD. Sebatian AA mempunyai formula molekul C3He0 dan memberikan keputusan yang positif menggunakan reagen Tollen. Tindak balas sebatian AA dengan larutan panas kalium permanganat, KMNO4 berasid menghasilkan sebatian BB. Penghidrogenan bermangkin bagi sebatian AA dengan nikel, Ni menghasilkan sebatian CC. Tindak balas sebatian BB dengan etanamina, CH3;CH2NH2 menghasilkan sebatian DD. (1) Draw the structural formula of compounds AA, BB, CC and DD. Lukiskan formula struktur bagi sebatian AA, BB, CC dan DD. (i) Name the type of chemical reaction for the formation of compound CC. Namakan jenis tindak balas kimia bagi penghasilan sebatian Cc.
In the Grignard reaction. The benzoic acid product (abbreviate PHCO2H) was separated from the impurity biphenyl (abbreviated Ph-Ph) through an extraction with aqueous NAOH which deprotonated benzoic acid and converted it into sodium benzoate (abbreviated PHCO2NA). After the Grignard reagent, phenylmagnesium bromide was mixed with CO2, it was mixed with additional ether and 6M H,SO4. This gave a two phase liquid mixture. What was dissolved in the top layer? Select all answers that are appropriate. There may be one or more. PHCO,H NaCI PHCO Na Ph-Ph PHCO,MgBr 00000
CH3 Ph3P-CHCH3 H3C H3C Aldehydes and ketones are converted into alkenes by means of a direct nucleophilic addition called the Wittig reaction. In the reaction, a triphenylphosphorine ylide, also called a phosphorane, adds to an aldehyde/ketone to give a four-membered cyclic intermediate called an oxaphosphetane. The oxaphosphetane is not isolated but instead spontaneously decomposes to release triphenylphosphine oxide and an alkene. Ph3P-CHCH3 H3C The ylide is formed by reaction of triphenylphosphine, a good nucleophile, with a primary alkyl halide in an S 2 reaction, followed by deprotonation of the carbon with a strong base, such as butyllithium. The carbonyl carbon and the carbon originally bonded to the halogen become the two carbons with the double bond in the product alkene :0: CH3 Com The real value of the Wittig reaction lies in its ability to yield an alkene of predictable structure, as the C-C bond is precisely where the C=O bond was in the reactant and no isomers (other than…
When CO2 is bubbled through an ether solution of benzylmagnesium bromide and the resulting mixture is acidified, phenylacetic acid is produced. Any unreacted benzylmagnesium bromide is converted to toluene in the acidification step. Write the complete reaction sequence for the process described above.
n-Pentanol (CH3CH2CH2CH2CH2OH) and 2-methylbutan-2-ol (CH3CH2C(CH3)2OH) are converted to their corresponding alkyl chorides on being reacted with hydrogen chloride. (a) Write out an equation for each reaction (b) Assign each the appropriate symbol (SN1 or SN2) (c) Write a suitable mechanism for each reaction
An unknown organic compound P has a molecular formula of CaHi60. P reacts with 2,4- dinitrophenylhydrazine but not with Tollen's reagent. P also reacts with iodine in sodium hydroxide to give yellow precipitate. On reduction, compound P produces a new compound Q. On heating the compound Q with concentrated sulphuric acid produces R which decolourises bromine in tetrachloromethane. Identify P, Q and R. Explain your reasoning. 10.