Use the Molecular Orbitals of the Trihydrogen Cation diagram and D3h character table to help you fill in the following:

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter7: Molecular Structures
Section: Chapter Questions
Problem 65QRT
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Use the Molecular Orbitals of the Trihydrogen Cation diagram and D3h character table to help you
fill in the following:
Gamma reducible for the SALCS of three 1s orbitals in H,
E
2C3
3C2
TRED
Transcribed Image Text:Use the Molecular Orbitals of the Trihydrogen Cation diagram and D3h character table to help you fill in the following: Gamma reducible for the SALCS of three 1s orbitals in H, E 2C3 3C2 TRED
The trihydrogen cation (H3") forms an equilateral triangle with Dah symmetry as shown on the
diagram below. It is not stable under "normal" conditions, but it has been found in the spectroscopic
data of interstellar gas clouds and planetary atmospheres. Use the information provided below to
answer the next series of questions.
D3h
2C 3C n
2s, 30,
A,'
1
1
1
v +L
E'
Az'
1
1
R,
(x, y) (x-y, xy)
A,"
1
H,* Molecule
A,"
E"
o(R, R,) (xz, yz)
-2
H,* MO Diagram
II
Energy
Transcribed Image Text:The trihydrogen cation (H3") forms an equilateral triangle with Dah symmetry as shown on the diagram below. It is not stable under "normal" conditions, but it has been found in the spectroscopic data of interstellar gas clouds and planetary atmospheres. Use the information provided below to answer the next series of questions. D3h 2C 3C n 2s, 30, A,' 1 1 1 v +L E' Az' 1 1 R, (x, y) (x-y, xy) A," 1 H,* Molecule A," E" o(R, R,) (xz, yz) -2 H,* MO Diagram II Energy
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