The standard electromotive force of the cell Pt(s)|H2(g)|HCl(aq)|AgCl(s)|Ag(s) has been determined from 0°C to 90°C, and the data were found to fit the expressionE/V = 0.237 – 4.856 × 10−4T(°C) − 3.421 × 10−6T2(°C) + 5.869 × 10−9T3(°C)Calculate the equilibrium constant, the standard reaction Gibbs energy, entropy and enthalpy for the cell reaction at 25°C. F = 96485 C mol-1AgCl(s) + ½H2(g) → Ag(s) + HCl(aq)

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Answered: The standard electromotive force of the…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter17: Electrochemistry And Its Applications

Section: Chapter Questions

Problem 38QRT

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The standard electromotive force of the cell Pt(s)|H₂(g)|HCl(aq)|AgCl(s)|Ag(s) has been determined from 0°C to 90°C, and the data were found to fit the expression

E/V = 0.237 – 4.856 × 10⁻⁴T(°C) − 3.421 × 10⁻⁶T²(°C) + 5.869 × 10⁻⁹T³(°C)

Calculate the equilibrium constant, the standard reaction Gibbs energy, entropy and enthalpy for the cell reaction at 25°C. F = 96485 C mol^-1

AgCl(s) + ½H₂(g) → Ag(s) + HCl(aq)

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