The specific rotation of optically pure adrenaline in water at 25°C is -53. If a chemist has a sample of synthetic adrenaline with a specific rotation of -45, calculate the enantiomeric excess.
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Q: 8. The specific rotation of (S)-carvone (at +20°C) is +61. A chemist prepared a mixture of…
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A: Solution Percentage of R(-) enantiomers : 26% Percentage of S(+) enantiomers : 74%
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Q: The specific rotation of (S)-2-iodobutane is +15.90°. Draw the structure of (S)-2-iodobutane.
A: Given The specific rotation of (S)-2-iodobutane is +15.90°. Draw the structure of (S)-2-iodobutane.
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Q: 2. The specific rotation of (S)-carvone (at 20°C) is +61. A chemist prepared a mixture of…
A: Given -> Specific rotation of (S)-carvone = +61 Observed rotation of mixture =-55°
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- The specific rotation (s) carvone (at 20°C) is +61. A chemist prepared a mixture of (R) carvone and its enantiomer, and this mixture had an observed rotation of -55. What is the specific rotation of (R)-carvone at 20°C?An attempt at synthesizing a certain optically-active compound resulted in a mixture of its enantiomers. The mixture had an observed specific rotation of +14.2°. If it is known that the specific rotation of the R enantiomer is -31.0°, determine the percentage of each isomer in the mixture. R enantiomer: % S enantiomer: %The pure D-form of a compound has a specific rotation (D line of sodium, 20° C) of +24°, whereas the pure L- form of the compound has a specific rotation (D line of sodium, 20° C) of -24°. If a scientist has a sample of this compound that is known to be 78% pure D-form (and, therefore, 100% - 78% pure L-form), what will be the observed rotation of this sample? Enter your answer to the nearest hundredth. The units are assumed to be degrees. 13.44
- Coibacin B (shown below) is a natural product that exhibits potent anti-inflammatory activity and potential activity in the treatment of leishmaniasis, a disease caused by certain parasites (Org. Lett. 2012, 14, 3878-3881): (a) Assign the configuration (R or S) of each chirality center (labeled A to C) in coibacin B. (b) Identify the number of possible stereoisomers for this compound, assuming that the geometry of the alkenes are fixed. Choices are given below and write the CAPITAL LETTER of your choice. A. 2 В. 4 С. 8 D. 16 ANSWERS: (a) A. В. C. (b)The specific rotation of (S)-carvone (at 20 degrees) is +61. A chemist prepared a mixture of (R)-carvone and its enantiomer, and this mixture had an observed rotation of -55. (a) What is the specific rotation of (R)-carvone at 20 degrees?Glutamic acid is a naturally occurring amino acid and isthe precursor to the food additive MSG (monosodium glutamate)which can cause allergic reactions in some people. If naturally occurring L glutamic acid has a melting point of 205 C and an optical rotation of + 31.5, what is the melting point and optical rotation of its enantiomer?
- The specific rotation of the S-enantiomer of a compound is -120°. What is the percentage of the R-enantiomer in a sample of the compound that has a measured specific rotation of –30°.The specific rotation of vitamin B7 in water (22°C) is +92°. A mixture of vitamin B7 and its enantiomer has a specific rotation of + 27.6°. What is the percentage of vitamin B7 and its enantiomer in this mixture? Select one: O A. 60% vitamin B7 : 40% enantiomer B. 65% vitamin B7 : 35% enantiomer C. 55% vitamin B7 : 45% enantiomer D. 70% vitamin B7 : 30% enantiomerHexahelicene seems a poor candidate for optical activity because all its carbon atomsare sp2hybrids and presumably flat. Nevertheless, hexahelicene has been synthesized and separated into enantiomers. Its optical rotation is enormous: [a]D = 3700°.Explain why hexahelicene is optically active, and speculate as to why the rotation isso large
- Glutamic acid is a naturally occurring amino acid and is the precursor to the food additive MSG (monosodium glutamate) which can cause allergic reactions in some people. If naturally occurring L glutamic acid has a melting point of 205 C and an optical rotation of + 31.5, what is the melting point and optical rotation of its enantiomer?Note: enantiomers have similar physical properties (mp, density, solubility), and same [a], but with different signs ( - or +). Practice: 1.2 gm sample of cocaine, [a], = -16º, was dissolved in 7.5 mL of chloroform and placed in a sample tube having a pathlength of 5 cm. what was the observed rotation in degrees?The specific rotation, [a]p, for (-)-malic acid is -27. What is the observed rotation for a solution of 0.75 g of (-)-malic acid in 10 mL of water in a sample tube having a pathlength of 10 cm? degrees. The observed rotation of a solution of 1.4 g of a compound in 10 mL of water is +1.3 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound? 9 more group attempts remaining Submit Answer Retry Entire Group