The organic bases cocaine pKb = 8.412 and codeine pKb = 7.952 react with hydrochloric acid to form salts (similar to the formation of NH4Cl by the reaction of NH3 and HCl). If solutions of the following salts have the same molarity, which solution would have the higher pH: cocaine hydrochloride, C H O NH+Cl-, or codeine hydrochloride, C H ClO NH+Cl-?  Show your step by step solution  and explanation of your solution.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section16.10: The Lewis Concept Of Acids And Bases
Problem 2.5ACP: To measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent...
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The organic bases cocaine pKb = 8.412 and codeine pKb = 7.952 react with hydrochloric acid to form salts (similar to the formation of NH4Cl by the reaction of NH3 and HCl). If solutions of the following salts have the same molarity, which solution would have the higher pH: cocaine hydrochloride, C H O NH+Cl-, or codeine hydrochloride, C H ClO NH+Cl-?  Show your step by step solution  and explanation of your solution.

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