The IR spectrum of 2-methyl-1-butanol (H;CCH,CH(CH;) CH,OH) and tert-butyl methyl ether [(CH;);COCH3] are shown below. Assign cach spectrum to the correct com- pound and identify the frequencies and the functional groups used to support your assignment. λ (μm) 6 7 8 9 10 11 12 1314 15 2.5 100 3 5 90 80 70 60 50 40 30 20 10 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Frequency (cm-1) A (µm) 7 8 9 10 11 12 13 14 15 2.5 100 3 5 20 4 6 90 80 70 60 50 40 30 20 10 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Frequency (cm¬!) (%) Transmission (%) Transmission 20

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
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Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 32P
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The IR spectrum of 2-methyl-1-butanol (H;CCH,CH(CH;)
CH,OH) and tert-butyl methyl ether [(CH;);COCH3] are
shown below. Assign cach spectrum to the correct com-
pound and identify the frequencies and the functional
groups used to support your assignment.
λ (μm)
6 7 8 9 10 11 12 1314 15
2.5
100
3
5
90
80
70
60
50
40
30
20
10
4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000
800
600
400
Frequency (cm-1)
A (µm)
7 8 9 10 11 12 13 14 15
2.5
100
3
5
20
4
6
90
80
70
60
50
40
30
20
10
4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000
800
600
400
Frequency (cm¬!)
(%) Transmission
(%) Transmission
20
Transcribed Image Text:The IR spectrum of 2-methyl-1-butanol (H;CCH,CH(CH;) CH,OH) and tert-butyl methyl ether [(CH;);COCH3] are shown below. Assign cach spectrum to the correct com- pound and identify the frequencies and the functional groups used to support your assignment. λ (μm) 6 7 8 9 10 11 12 1314 15 2.5 100 3 5 90 80 70 60 50 40 30 20 10 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Frequency (cm-1) A (µm) 7 8 9 10 11 12 13 14 15 2.5 100 3 5 20 4 6 90 80 70 60 50 40 30 20 10 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Frequency (cm¬!) (%) Transmission (%) Transmission 20
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