The interfacial tension y of the interface between mercury and an aqueous solution of an ectrolyte was measured as a function of potential difference AE: ΔΕ / mV 100 50 0 100 200 300 400 500 600 700 800 900 1000 1200 325 345 360 378 388 394 391 383 373 362 350 335 318 270 E is defined as the difference between the applied potential and the potential of zero charge r mercury in aqueous sodium fluoride. 1 Nm-1

Fundamentals Of Analytical Chemistry
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Chapter21: Potentiometry
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Problem 21.11QAP
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c) The interfacial tension y of the interface between mercury and an aqueous solution of an
electrolyte was measured as a function of potential difference AE:
ΔΕ /
mV
100 50 0
100 200 300 400 500 600 700 800 900 1000 1200
325 345 360 378 388 394 391 383 373 362 350 335
383 373 362 350 335 318 270
AE is defined as the difference between the applied potential and the potential of zero charge
for mercury in aqueous sodium fluoride.
Graphically determine the potential of zero charge in the experimental electrolyte.
Y/
Nm-1
Transcribed Image Text:c) The interfacial tension y of the interface between mercury and an aqueous solution of an electrolyte was measured as a function of potential difference AE: ΔΕ / mV 100 50 0 100 200 300 400 500 600 700 800 900 1000 1200 325 345 360 378 388 394 391 383 373 362 350 335 383 373 362 350 335 318 270 AE is defined as the difference between the applied potential and the potential of zero charge for mercury in aqueous sodium fluoride. Graphically determine the potential of zero charge in the experimental electrolyte. Y/ Nm-1
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