The correct statement(s) for the following addition reactions is (are) H3C H. 1. BD3-THF i) M and N 2. H2O2, OH CH3 H3C CH3 1. BD3 THF ii) O and P 2. H2O2, OH" H. H. [0] and [P] are identical molecules [M] and [N] are enantiomers First reaction yields racemic mixture; whereas second reaction yields meso isomers Total three fractions obtained, when we distilled product mixture of both the reactions
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![The correct statement(s) for the following addition
reactions is (are)
H3C
1. BD3 THF
i)
M and N
2. H2O2, OH
CH3
H3C
CH3 1. BD3 THF
ii)
O and P
2. H2О, ОН-
H
[0] and [P] are identical molecules
[M] and [N] are enantiomers
First reaction yields racemic mixture; whereas
second reaction yields meso isomers
Total three fractions obtained, when we distilled
product mixture of both the reactions](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffcfefdcf-9f43-4ff6-9df0-235df5f775a0%2F2d5fa81b-bc2a-4707-b45f-99b26892cd7d%2Fkgy8v36_processed.jpeg&w=3840&q=75)
Trending now
This is a popular solution!
Step by step
Solved in 2 steps
