The cations formed during 1,2 and 1,4 addition are different in energy due to their substitution patterns. True False

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter7: Cycloalkanes
Section: Chapter Questions
Problem 15E
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The cations formed during 1,2 and 1,4 addition are different in energy due to their substitution
patterns.
True
False
Transcribed Image Text:The cations formed during 1,2 and 1,4 addition are different in energy due to their substitution patterns. True False
How do you determine which orbital is the HOMO/LUMO?
First, count the total number of pi electrons. Divide that number by 2 and the number you get tells
you which orbital is the HOMO. The orbitals would be numbered from lowest energy to highest
energy for correlation.
First, determine the number of molecular pi orbitals. Then, count the total number of pi electrons.
Fill in the orbitals from low energy to high energy by pair electrons until you use all electrons.
Then, that indicates the HOMO/LUMO.
Transcribed Image Text:How do you determine which orbital is the HOMO/LUMO? First, count the total number of pi electrons. Divide that number by 2 and the number you get tells you which orbital is the HOMO. The orbitals would be numbered from lowest energy to highest energy for correlation. First, determine the number of molecular pi orbitals. Then, count the total number of pi electrons. Fill in the orbitals from low energy to high energy by pair electrons until you use all electrons. Then, that indicates the HOMO/LUMO.
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