Suppose the reduction of nitric oxide proceeds by the following mechanism: step elementary reaction rate constant 1 |H, (g)+2NO (g) → N,0 (g) + H,0 (g) H, (g) + N,0 (g) → N2 (g) + H,0 (g) k2 Suppose also k, « k,. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. rate = k U Note: your answer should not contain the concentrations of any intermediates.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
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Suppose the reduction of nitric oxide proceeds by the following mechanism:
step
elementary reaction
rate constant
1 H, (g) + 2NO (g) → N,0 (g)+ H,0 (g)
k1
H, (g) + N,0 (g) → N2 (g) + H20 (g)
k2
Suppose also k, « k,. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
rate = k||
Note: your answer should not
contain the concentrations of
any intermediates.
Transcribed Image Text:Suppose the reduction of nitric oxide proceeds by the following mechanism: step elementary reaction rate constant 1 H, (g) + 2NO (g) → N,0 (g)+ H,0 (g) k1 H, (g) + N,0 (g) → N2 (g) + H20 (g) k2 Suppose also k, « k,. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. rate = k|| Note: your answer should not contain the concentrations of any intermediates.
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