Suppose the formation of nitryl fluoride proceeds by the following mechanism:stepelementary reaction1 NO₂ (g) +F₂ (g) → NO₂F (g)+F (g)2F (g) + NO₂ (g) → NO₂F (g)Suppose also k₁ << k₂. That is, the first step is much slower than the second.Write the balanced chemicalequation for the overallchemical reaction.Write the experimentally-observable rate law for theoverall chemical reaction.Note: your answer should notcontain the concentrations ofany intermediates.0rate = &rate constantk₁k₂

Answered: Image /qna-images/answer/f7dd004d-9ba6-43c5-b063-90e33107eb85.jpg

Suppose the formation of nitryl fluoride proceeds by the following mechanism: elementary reaction rate constant NO₂ (g)+F₂ (g) → NO₂F (g) +F (g) 1 k₁ F (g) +NO₂ (g) NO₂F (g) k₂ Suppose also k₁ <

Suppose the formation of nitryl fluoride proceeds by the following mechanism: elementary reaction rate constant NO₂ (g)+F₂ (g) → NO₂F (g) +F (g) 1 k₁ F (g) +NO₂ (g) NO₂F (g) k₂ Suppose also k₁ <

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter16: Thermodynamics: Directionality Of Chemical Reactions

Section16.5: Entropy And The Second Law Of Thermodynamics

Problem 16.6CE

See similar textbooks

Related questions

Q: How many grams are in 2.3 x 104 moles of calcium phosphate, Ca3(PO3)2? How many moles are in 3.4 x…

A: 15 ) given moles of calcium phosphate = 2.3 *10-4 moles molar mass of calcium phosphate = 310.18…

Q: Calculate the change in internal energy (ΔE, in kJ) for a system that gives off 25.0 kJ of heat and…

Q: Formal charges and bonds are shown correctly in this Lewis structure, but lone pairs might be drawn…

A: Lone pairs, also known as non-bonding electron pairs, are pairs of electrons in a molecule that are…

Q: If a chemical reaction has a positive AH and a positive AS, then A) it will be spontaneous at all…

Q: 1. Perform the following: a. Write the formula for copper (II) phosphate.. b. Calculate the…

A: Here we calculate the chemical formula using the charge neutral method. Then we calculate molar mass…

Q: What is the IUPAC name for the compound shown? x

A: Consider the given information as follows; IUPAC name of the compound =?

Q: Compound A on ozonolysis yields the two products shown. What is the structure of compound A? OOOO OI…

A: we have to determine the structure of compound A

Q: 4. For each of the following identify the valence electrons and draw the orbital filling diagram of…

A: For any elements the number of electrons in the outer most shell is known as valence electrons.…

Q: A. Glucose is considered a when compared to CO2 which is a highly compound. B. Good electron donors…

A: Electrochemistry fill in the blanks.

Q: At a certain temperature this reaction follows second-order kinetics with a rate constant of 2.81 M…

A: Given -> Rate constant (k) = 2.81 M-1.s-1 Initial concentration of NH4OH = 0.240 M Time (t) =…

Q: At equilibrium, a 1.0 L reaction vessel contains 2.3 mol of Mg(OH)2 and 0.170 mol of OH. What is the…

Q: What is the reaction order? 02 0 01 [A]o =

A: Order of a chemical reaction refers to the exponent in its rate equation. The rate equation…

Q: A step-by-step example of performing a scientific method from an experiment plating fruits and…

A: The scientific method is a systematic approach to solving problems and answering questions through…

Q: Write the mechanism of imine formation through aminoalcohol reacting butanone with aniline (C6H5NH2)…

A: Imine bond is -C=NH Amino alcohol intermediate is -C(OH)-NH- The lone pair on N atom of Aniline…

Q: An effective collision depends on two factors: a) The polarity of the molecules and the size of the…

A: We have to select the 2 factors for an effective collision

Q: Calculate the amount of heat needed to melt 181. g of solid hexane (C6H₁4) and bring it to a…

A: Given , mass of solid hexane = 181. g

Q: Provide the correct common name for the compound shown here. 4- trans- cis- 3- 2- 1- cyclo tert-…

A: The given compound contains one six membered ring. The number of carbons in the substituents are…

Q: Bottled straight-chain alkanes can be used as fuels, including pentane and hexane . pentane…

A: Explanation Released of large amount of energy makes hydrocarbon as good fuels. Here ΔΗ°comb for…

Q: Draw the sigma complex for the formation of the bromonium electrophile with proper resonance forms…

A: Given that, We have to draw the structure of the Sigma complex form from the above two products.…

Q: 1A H 2A Li Be Na Mg 38 48 58 68 78881B 2B Al K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Shell 1 : 2 Shell…

A: Answer: In a chemical reaction every atom tries to have an electronic configuration like a noble gas…

Q: Consider the following reaction: SO2(g) + 1/2 O2(g) → SO3(g) Calculate ΔGorxn (in kJ) at 298 K.…

A: To determine delta G , first we will calculate deltaH and deltaS for reaction . After that we will…

Q: We are doing an experiment on measuring the temperature. We are to measure the temperature of hot…

A: The experiment you are conducting involves measuring the temperature of hot water and water with…

Q: 46. "Proton hopping" essentially means that: B) A) an individual proton "jumps" from one…

A: As per the rule, we can only answer the first question. Proton hopping is a transfer ( or hopping…

Q: nsider the compound. What is the IUPAC name for the compound shown? Spelling and punctuation count.…

A: The organic compound is given and we have to tell the IUPAC name of the compound.

Q: What is the activation energy for the isomerization of methyl isocyanide? Rate Constant Temperature

Q: Compound ΔHf° (kJ/mol) CH3OH(l) –238.7 O2(g) 0.00 CO2(g) –393.5 H2O(l) –285.8 How many grams of…

Q: Draw all important resonance structures of each ion. O-H 3 CH₂ ستعمال

Q: This compound has an important resonance structure. Draw the resulting resonance structure according…

A: Definition of Resonance structure : Resonance structures are the structure that are represented by…

Q: 5. Show the product(s) of the following reactions A Br2, CCl4 B C KMnO4, OH cold, dilute OsO4, H₂O2

A: Different sets of substrate and reagent gives Different types of products. Br2 gives Trans dibromo…

Q: 4. Label the following groups in the periodic table: Alkaline Earth Metals, Onoble gases, alkali…

A: As per the student's request I'm solving only question number 4. We know that the periodic table is…

Q: 15. Membrane structures are maintained primarily by: a. Dipolar interactions b. Hydrophobic…

A: Membrane structures are maintained primarily by hydrophobic interactions. Hydrophobic interactions…

Q: 18. A compound is known to have a free amino group with a pK, of 8.8, and one other ionizable group…

A: Given that: Volume of solution = 100 mL Concentration of solution = 0.2 M Volume of HCl = 40 mL…

Q: Rank the boiling points of the molecules shown below from lowest to highest.

A: Amines have higher boiling points than those of alkanes of similar molar mass because they can…

Q: (a) H₂O₂ → H₂O + O (b) Br+ Br + M (c) NO₂ + NO₂ Br₂ + M 2 NO + 0₂ unimolecular bimolecular…

A: Molecularity is a term used to describe the number of species involved in the rate-determining step…

Q: 2. Consider a layer of oil floating on top of a layer of water. Where would you expect to find the…

A: a. Triglycerides would typically be found in the oil phase, as they are the main component of many…

Q: gold bar of unknown amount absorbs 1.09 kJ of heat and raises its temperature from 5.3 °C to 72.2…

A: Heat absorbed, q = mCs∆T ∆T = T2 - T1 T1 = Initial temperature T2 = Final temperature m = Mass of…

Q: C. d. e. CH3 CH₂CH₂CHCH3 + Br₂ CH3, + Reactivity of Hydrocarbons + KMnO4 KMnO4 UV light

A: We know that the difference set of reactant and reagents form different types of product for the…

Q: Consider a hypothetical chemical reaction: A+B C+D (In this equation A, B, C and D stand for some…

A: The progress of a reaction can be represented by the reaction coordinate diagram. In a reaction…

Q: What is the predicted product of the reaction shown? H IV H 1. excess 03 2. (CH3)2S H || H V H H III

Q: Identify the limiting reactant in the reaction of hydrogen and iodine to form HI, if 4.33 g of H₂…

A: Hydrogen reacts with iodine to form hydrogen iodide. The equation for the balanced chemical reaction…

Q: For the reaction: 2 A (g) + B (s) ⇌ 2 C (s) + D (g) At 298 K in a 10.0 L vessel, the equilibrium…

A: We have find out the value of the equilibrium constant for the given reaction.

Q: Given the following data for the hydrate M(NO3)3 dot X H₂O, where M is a metal with the atomic mass…

A: Given that the hydrate is M(NO3)3 . XH2O. The molar mass of M is 36.81 g/mol.

Q: In an endothermic reaction the enthalpy of the reactants is greater than the enthalpy of the…

A: Endothermic and exothermic reactions are two types of chemical reactions that differ based on the…

Q: Predict the products by showing the reaction mechanism (arrow pushing) of the given diagram. 1.…

A: The organic compound in which a double bond is present between two carbon atoms is known as an…

Q: Which one of the following compounds is consistent with the mass spectrum below? Relative Intensity…

A: The instrumental method which is used to determine the structure of an unknown compound by analyzing…

Q: 4:00 Step 1 Step 2 Question 10 of 13 H₂(g) + 2NO(g) → N₂O(g) + H₂O(g) (slow) N₂O(g) + H₂(g) → N₂(g)…

A: The rate of a chemical reaction is a measure of how fast the reaction occurs. It is defined as the…

Q: Which of the reactions shown can be used to make the given compound? OCH₂ OH H NaOCH₂ OH LOCH3…

A: The given compound is formed from carbonyl containing reactant having OH group ( means this given…

Q: Two objects are brought into contact. Object #1 has mass 0.97 kg, specific heat capacity 0.24 J g-¹…

A: When the thermal equilibrium is reached, Heat released by object #1 = Heat absorbed by object #2

Q: Linear Measurements 2 3 23 48 4 5 24 cm 24.145 6 cm 11-481-750 25 = 0.05 49 25-21 1 = 0.1 ack space…

A: The measurements for the three scales according to their position in scale is given below

Q: Determine the relation between the osmotic pressure and the concentration of solute. Compare your…

A: The osmotic pressure, π, of a solution is a measure of the pressure required to prevent the flow of…

Question

Suppose the formation of nitryl fluoride proceeds by the following mechanism:
step
elementary reaction
1 NO₂ (g) +F₂ (g) → NO₂F (g)+F (g)
2
F (g) + NO₂ (g) → NO₂F (g)
Suppose also k₁ << k₂. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
0
rate = &
rate constant
k₁
k₂

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Old-fashioned smelling salts consist of ammonium carbonate, (NH4)2CO3. The reaction for the decomposition of ammonium carbonate (NH4)2CO3(s)2NH3(g)+CO(g)+H2O(g) is endothermic. Would the smell of ammonia increase or decrease as the temperature is increased?
Monochloroethane (C2H5Cl) can be produced by the direct reaction of ethane gas (C2H6) with chlorine gas or by the reaction of ethylene gas (C2H4) with hydrogen chloride gas. The second reaction gives almost a 100% yield of pure C2H5Cl at a rapid rate without catalysis. The first method requires light as an energy source or the reaction would not occur. Yet G for the first reaction is considerably more negative than G for the second reaction. Explain how this can be so.
The following equation represents a reversible decomposition: CaCO3(s)CaO(s)+CO2(g) Under what conditions will decomposition in a closed container proceed to completion so that no CaCO3 remains?
Silicon forms a series of compounds analogous to the al-kanes and having the general formula SinH2n+2. The first of these compounds is silane, SiH4, which is used in the electronics industry to produce thin ultrapure silicon films. SiH4(g) is somewhat difficult to work with because it is py-ropboric at room temperature—meaning that it bursts into flame spontaneously when exposed to air. (a) Write an equation for the combustion of SiH4(g). (The reaction is analogous to hydrocarbon combustion, and SiO2 is a solid under standard conditions. Assume the water produced will be a gas.) (b) Use the data from Appendix E to calculate ? for this reaction. (c) Calculate G and show that the reaction is spontaneous at 25°C. (d) Compare G for this reaction to the combustion of methane. (See the previous problem.) Are the reactions in these two exercises enthalpy or entropy driven? Explain.
In Chapter 3, we discussed the conversion of biomass into biofuels. One important area of research associated with biofuels is the identification and development of suitable catalysts to increase the rate at which fuels can be produced. Do a web search to find an article describing biofuel catalysts. Then, write one or two sentences describing the reactions being catalyzed, and identify the catalyst as homogeneous or heterogeneous.
Substances that poison a catalyst pose a major concern for many engineering designs, including those for catalytic converters. One design option is to add materials that react with potential poisons before they reach the catalyst. Among the commonly encountered catalyst poisons are silicon and phosphorus, which typically form phosphate or silicate ions in the oxidizing environment of an engine. Group 2 elements are added to the catalyst to react with these contaminants before they reach the working portion of the catalytic converter. If estimates show that a catalytic converter will be exposed to 625 g of silicon during its lifetime, what mass of beryllium would need to be included in the design?
The recycling of polymers represents only one industrial process that allows creating order in one location by creating greater disorder at some other location, often at a power plant. List three other industrial processes that must create disorder in the surroundings to generate the desired material.
Which reaction mechanism assumptions are unimportant in describing simple ionic reactions between cations and anions? Why?
During polymerization, the system usually becomes more ordered as monomers link together. Could an endothermic polymerization reaction ever occur spontaneously? Explain.
The reaction of carbon monoxide with hydrogen to form methanol is quite slow at room temperature. As a general rule, reactions go faster at higher temperatures. Suppose that you tried to speed up this reaction by increasing the temperature. (a) Assuming that rH does not change very much as the temperature changes, what effect would increasing the temperature have on rSsurroundings? (b) Assuming that rS for a reaction System does not change much as the temperature changes, what effect would increasing the temperature have on rSuniverse?
Why are there no changes specified for Ni in Exercise 13.61, part (f)? What property of Ni does change?
5.12. True or false: If all the partial pressures of reactants and products drop by half, the value of Q drops by half. Give an example of a chemical reaction to support your answer.

SEE MORE QUESTIONS

Recommended textbooks for you

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

Chemistry for Engineering Students

Chemistry

ISBN:

9781337398909

Author:

Lawrence S. Brown, Tom Holme

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781133611097

Author:

Steven S. Zumdahl

Publisher:

Cengage Learning

General Chemistry - Standalone book (MindTap Cour…

Chemistry

ISBN:

9781305580343

Author:

Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Publisher:

Cengage Learning

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

Chemistry for Engineering Students

Chemistry

ISBN:

9781337398909

Author:

Lawrence S. Brown, Tom Holme

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781133611097

Author:

Steven S. Zumdahl

Publisher:

Cengage Learning

General Chemistry - Standalone book (MindTap Cour…

Chemistry

ISBN:

9781305580343

Author:

Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Publisher:

Cengage Learning

SEE MORE TEXTBOOKS