Specify the most important fragmentation paths for ester. Rested spectrum is occupied by the ethyl ester.

General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter16: Carboxylic Acids, Esters, And Other Acid Derivatives
Section: Chapter Questions
Problem 16.120EP
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There are given five different massspectors of ester with the molecular formula CH1202. One of the compounds is an
ethyl-ester, the other four are methyl-esters.
100
A
74
41
80
43
60
59
39
29
57
40
27
85
101
20
20
40
60
80
100
120
100
C
100
74
43
71
29
80
80
43
29
60
60
57
85
27
41
88
40-
27
87
40-
59
20
20
101
120
100-
E
20
40
60
80
100
20
40
60
80
100
120
100
57
57
88
80
80
29
60
60
41
41
29
40
40
56
85
101
20
20-
85
101
20
40
60
80
100
120
40
60
80
100
120
Tip: start with drawing structural formulas for the possible molecules:
a. Specify the most important fragmentation paths for ester.
b. Rested spectrum is occupied by the ethyl ester.
Transcribed Image Text:There are given five different massspectors of ester with the molecular formula CH1202. One of the compounds is an ethyl-ester, the other four are methyl-esters. 100 A 74 41 80 43 60 59 39 29 57 40 27 85 101 20 20 40 60 80 100 120 100 C 100 74 43 71 29 80 80 43 29 60 60 57 85 27 41 88 40- 27 87 40- 59 20 20 101 120 100- E 20 40 60 80 100 20 40 60 80 100 120 100 57 57 88 80 80 29 60 60 41 41 29 40 40 56 85 101 20 20- 85 101 20 40 60 80 100 120 40 60 80 100 120 Tip: start with drawing structural formulas for the possible molecules: a. Specify the most important fragmentation paths for ester. b. Rested spectrum is occupied by the ethyl ester.
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