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- 2) mny Starting mater 1al and product. Provide condihons for a reaction when givern I. 3) HHa) " -78 °C, THE 2) H₂0 Phyp THF, 0'C 8 TICH MICH reflujoFor the reaction below, draw a step-by-Step mechanism (ar rOus men drawa reaction Coordinate diagram as well as mě Struckare of she ransHlon state m for the reacon mechanism for the first Step in the mechanism consist ent with me Hammond Postulate : Но -Br CH gCH2OH + HBr
- (c) (d) Н (e) НО HO ОН н Na₂Cr₂O7 H2SO4, H2O 1. LiAIH4 2. H2O workup 3. PCC 4. (Ph)3PCH2 OH H2SO4 (catalytic)The following energy diagrams for SAE reactions are correct, except:Identify the reagent used in the following transformation: OH P Q HO HO P = LIAIH, Q = KMNO, Q = MnO, / CH,Cl, Q = Ag,CO, on celite, PhH (A) (B) P= NABH, /MeOH %3D (C) P=CeCl,.7H,O (D) P= NABH, /CeCl,.7H,0 , / CeCly.7H,O Q = MnO, / CH,Cl,
- 5-52 The following syntheses have flaws in them. What is wrong with each? (a) .CH3 .CO2H 1. Cl2, FeCl3 2. KMNO4 CI (b) CІ CI. 1. (CH3)3CCI, AICI3 2. KMNO4, H2O CO2HPrediga los productos de las siguientes reacciones. (a) éter sec-butil isopropflico + HBr conc., calor (c) éter di-n-butflico + NaOH conc. caliente (e) etoxibence no + HI conc., calor (b) 2-etoxi-2-metilpentano + HBr conc., calor (d) éter di-n-butllico + Na metálico (1,2-epoxihexano+H*,CH,OH(b) Predict the product in the following reaction under the given reaction conditions: ond (a) Ces i) n-Buli, -80°C II) NHẠCH CH₂Cl₂, MeLi UNIT-IV 7. Giving justification, predict the product(s) (major and minor; if any) in the following reactions: C₂H5OH/ OC₂H5