Reaction of an ester with DIBAH/toluene/-78°C followed by H3O* yields which ofthe following functional groups?esterO aldehydealcoholketone

Answered: Image /qna-images/answer/71e049f2-2f4b-490d-a74a-33c53f645eb6.jpg

Answered: Reaction of an ester with…

Reaction of an ester with DIBAH/toluene/-78°C followed by H3Ot yields which of the following functional groups? ester aldehyde alcohol O ketone

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 41AP

See similar textbooks

Related questions

Q: Nitric oxide reacts with chlorine gas according to the following reaction: 2 NO (g) + Cl2 (g) = 2 NO...

Q: The water gas shift reaction below is used in the production of hydrogen. CO +H,O → CO, +H, 2 g 2(g)...

Q: Chemistry Q. compare normal maize and potato starch, which one gives a clear paste ? explain your an...

A: Potato starch has the highest viscosity of any of the commercially available starches. It is a sligh...

Q: A gas has a pre: pressure?

Q: thermometer A sample of quartz, which has a specific heat capacity of 0.730 J'g c, is put into a cal...

Q: please explain to understand the process!!! Given the following information: PCI3(1) + Cl2(g) → PCI5...

A: delta H is a extensive property....

Q: please compute for theoretical yield, actual yield, and percentage yield * Weight MW Theoretica...

Q: ewis structures shown contains one polar covalent bond. Identify the bond, and use th olarity.

A: Polar covalent bond is formed when atoms having different electronegativity share electrons in a cov...

Q: While ethanol (CH,CH,OH) is produced naturally by fermentation, e.g. in beer- and wine-making, indus...

Q: Calculate the pH during the titration of 20.00 mL of 0.1000 M dimethylamine, (CH3)2NH(aq), with 0.10...

Q: Gaseous ethane (CH,CH,) reacts with gaseous oxygen gas (0,) to produce gaseous carbon dioxide (Co,) ...

Q: Assuming the net reaction is an exothermic process. Which of the potential energy diagrams best repr...

A: The net reaction is assumed to be exothermic in nature. This is a nucleophilic substitution reaction...

Q: You are studying a clear solution and you added the pH indicator methyl violet. The colour range of ...

A: The color of a solution of pH 0.2 is needed to be determined on the addition of an acid-base indicat...

Q: Give the chemical equation for the combustion of cyclohexene and the combustion of cyclohexene (for ...

Q: Is high or low electronegativity associated with increased metal reactivity?

Q: If 28.5 g. of Ca(OH)2 is dissolved in enough water to make 185 g. solution. Calculate the % concentr...

Q: CH3-Br (а) 'N: CH2=CH-C-H (b) ОН (с) 2 CH3-CH2-C-H

A: Due to presence of 'N' conjugation with double bond , it acts as nucleophile. After the reaction it ...

Q: Calculate the kinetic energy of a 0.16 kg baseball moving at a speed of 25.0 Round your answer to 2 ...

A: Given that, the mass of a baseball is m = 0.16 kg. The speed of the it is v = 25.0 m/s. We have to c...

Q: You are given a metal and asked to identify it by determining its specific heat. You place the metal...

Q: If 27.1 grams of bromine and 12.0 grams of chlorine combine to form bromine monochloride, how many g...

A: Given :- Bromine + chlorine ---> bromine monochloride Mass of Br2 = 27.1 g Mass of Cl2 = 12.0 ...

Q: A brick has a mass of 4.0 kg and the Earth has a mass of 6.0 x 1o g. Use this information to answer ...

A: Please find your solution below : The mole is a quantity that defines the amount of a substance and ...

Q: Assume that all solution were prepared at 25℃, and the solutes were completely dissolved. Alcoholic...

Q: A mixture of helium and oxygen gas is expanded from a volume of 47.0L to a volume of 91.0 L, while t...

Q: 4. Calculate gas compressibility factors and densities of a 0.65-specific gravity gas at 150 F and 5...

A: _

Q: Which of the following glucose solutions has a molarity of 0.60 M? Group of answer choices A. 0.050 ...

A: • We have to select the option in which the glucose solution has a molarity of 0.60 M

Q: Provide the products for the below reactions: HgSO4 H,SO4 ВНЗ, ТHF H2O2, OH", H2O

A: HgSO4 and aqueous dilute H2SO4 is used for alkyne hydration. Alkynes hydration is much harder than a...

Q: Calculate the pH when 1.35 g of C6H5COONa (FW = 144.1 g/mol) is added to 38 mL of 0.50 M benzoic aci...

A: The pH can be calculated as follows

Q: An unknown compound has the following chemical formula: Fe(NO,), where x stands for a whole number. ...

A: Molecular formula: In a molecular formula we describe the number of atoms of all the elements presen...

Q: A mixture of He, Ne, and Ar has a pressure of 28.2 bar at 28.0 °C. The partial pressure of He is 2.7...

A: given :- partial pressure of He = 2.74 bar partial pressure of Ar = 1.15 bar total pressure of mix...

Q: 3) Which product would be isolated from the reaction shown? Draw the reaction mechanism. 1. BH3/THF ...

A: Here the alkyne acts as nucleophile and BH3 acts as electrophile and the reaction occur between thes...

Q: A chemist determined by measurements that 0.015 moles of gallium participated in a chemical reaction...

Q: Write the chemical equation for the solution of calcium hydroxide in water.

Q: Determine the pH at the equivalence (stoichiometric) point in the titration of 44.27 mL of 0.138 M m...

A: Given data : Concentration of morphine = 0.138 M Volume of morphine = 44.27 mL Concentration of HCl ...

Q: A chemical engineer is studying the following reaction: HCH;CO,(aq)+CH,NH,(aq) → - CH;CO,(aq)+CH;NH(...

A: Qc and Kc are calculate the same way, but Qc is used to determine which direction a reaction will pr...

Q: can you please draw the mechanism to form the product shown? OH Ме, OH B. 1. CrO3, pyridine, H2O 2. ...

Q: EDTA Tiration Cures: 11.6. A lo0nL sohntion q0.050MM' buffered to pH q.00 was tifrated rith 0. OSD O...

Q: Calculate the number of nitrogen atoms in a 140.0 g sample of dinitrogen tetroxide (N,04). Be sure y...

A: We have to calculate the number of nitrogen atoms in a 140.0 g sample of dinitrogen tetraoxide (N2O4...

Q: Describe the formation of metal complex with octahedral geometry using all the orbitals of same ener...

A: The formation of an octahedral complex using the orbitals of same energy level. Since you have as...

Q: Magnesium hydroxide is poorly soluble in pure water but dissolves quite well in pH 7.0 buffer. This ...

A: We would first write solubility equation of Magnesium hydroxide and use the significance of buffer s...

Q: The compound potassium cyanide is a strong electrolyte. Write the reaction when solid potassium cyan...

A: When strong electrolyte is added to water , it breaks into its corresponding ions . equation is give...

Q: 13.14 Suggest likely products for the following reactions: (а) ВСl; + EiOH —- (b) BF, + E1OН —— (c) ...

A: The correct answer is given below

Q: The peptide below is placed into a buffer with a pH = 1.54 -NH-CH-C HO- H;N-CH- CH2 -NH -CH-C -NH-CH...

A: We have to find out the direction of movement of peptide at pH=1.54

Q: 1. -MgBr H,0* workup LOTMS 2. ТВАF 3. POCI, / pyridine (excess) 4. Нeat

A: NOTE: There is some problem in question (either reactant carbon atoms or in reagent given). Here I'm...

Q: One method used in the eighteenth century to generate hydrogen was to pass steam through red-hot ste...

A: Given that, a reaction is 3Fes+4H2Og→Fe3O4s+4H2g. The molar masses are Fe = 55.845 g/mol, H2O = 18....

Q: Liquid hexane (CH, (CH,(CH,),CH;) • reacts with gaseous oxygen gas (o, to produce gaseous carbon dio...

Q: Calculate the pH during the titration of 40.0 mL of 0.25 M HI with 0.25 M RbOH after 38.28 mL of the...

Q: Find the Barometric Pressure (torr) and the Vapor Pressure of Water at the Appropriate T (torr) Giv...

A: Pressure has several units and some of them are torr and mmHg which are related to one another as 1 ...

Q: What are the basic chemistry apparatuses? Include meaning.

A: 1.A beaker is a common container in most labs. It is used for mixing, stirring, and heating chemical...

Q: A chemist determined by measurements that 0.0600 moles of gold participated in a chemical reaction. ...

A: • The values provided in the question are:- i) Number of moles of gold participated in a chemic...

Q: Calculate the pH during the titration of 20.0 mL of 0.25 M HBr(aq) with 0.25 M LiOH after 20.51 mL o...

Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

Reaction of an ester with DIBAH/toluene/-78°C followed by H3O* yields which of
the following functional groups?
ester
O aldehyde
alcohol
ketone

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Provide the major organic product of the following reaction. but-1-yne 1) Sia₂BH 2) H₂O₂, OH What is it called when an enol converts to a keto? A) Keto-enol isomerism B) Keto-enol tater tot-ism C) Keto-enol conversion D) Keto-enol tautomerism
Which of the following is an acetal? H3C H;C но CH3 CH3 H3C- H3C H3C H3C OH А C A and C B and D A O A, B, and D D B.
Which of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A D
Pick the best IUPAC name for the following molecule: H3C-O CH3 CH3 H3C- O 2,4,5-trimethylheptanal O5-methoxy-2,4-dimethylheptanoic Acid O 5-methoxy-2,4-dimethylheptanal 5-methoxy-2,4-dimethylheptan-1-ol
What is the correct assignment of the names of the following ketones? H;C CH3 CH3 1 2 O 1 = acetone; 2 = phenol; 3 = benzaldehyde 1 = acetone; 2 = acetophenone; 3 = benzophenone %3D %3D O 1 = formaldehyde; 2 = benzaldehyde; 3 = acetophenone %3D O 1 = acetaldehyde; 2 = acetophenone; 3 = benzaldehyde %3D %3D
What is the product of the following reaction sequence? II CH;CH2CCH; Но* Mg CH;CH2CH2B O 3-methyl-3-hexanol O 2-methyl-3-hexanol 3-ethyl-2-pentanol 2-heptanol
Show how to convert ketones and aldehydes to other functional groups, anddevise multistep syntheses using ketones and aldehydes as starting materialsand intermediates.
10) Provide an unambiguous name for the following compound. OH
What is the purpose of a slyl ether? O To prevent the formution df carbonic acids To protect ketones from orgnometalic reagerts and uther magents O To protect esters from organometalic reaperts and otbe rapts O To protect alkcohols from orpinometalic ragerts and other prts
Draw the principal organic product for the reaction of 1-bromopentane with lithium in diethyl ether, followed by formaldehyde in diethyl ether, and then followed by dilute acid.
For following substituted benzenes: [1] C6H5Br; [2] C6H5CN; [3] C6H5OCOCH3: Does the substituent activate or deactivate the benzene ring inelectrophilic aromatic substitution?
Rank the reactivity of the compounds below toward nucleophilic acyl substitution by writing the compounds' letters in the proper blanks in the box below. `NH CI Br CH3 CH3 A В C E rank compounds for acyl substitution reactivity most least reactive reactive