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- IR spectroscopy does not distinguish very well betweenisomers I and J. Explain why. How could UV–vis spectroscopy be used to distinguish between themHow can IR spectroscopy be used to distinguish between each pair of isomers?The picture shows the structure of Se analog of an Sg-ring structure, and the atoms are also numbered. Using the information, determine the number of signals in "Se (where I = ½,7.6%) NMR spectrum of the compounds considering the substitution of Se in indicated S positions. 8 Se substitutions in Position 1 and Position 3. b. Se substitutions in Position 1, Position 2, and Position 4. Se substitutions in Position 1 and Position 2. а. с.
- Rank the following compounds according to their reactivity to HCN and justify why10) The following spectra correspond to xylenes (dimethylbenzenes) ortho, meta and para. Which corresponds to which?The 1HNMR signals the alkene protons of three ethylene derivatives with different substitution patterns are shown below. Considering that each of the derivatives contains AT MOST two substituents (X and/or Y) and at least two protons. A) Propose the possible substitution patterns for each of the derivatives based on the observed splitting patterns. Justify your proposals B) How might one differentiate between the three possible isomers of derivative 3 in the question above using 1H NMR spectroscopy? Explain in a sentence – no calculation is needed. C) Give TWO methods that can be used to differentiate between the three possible isomers of derivative 2 in the question above using 1H NMR spectroscopy? Explain in a sentence – no calculation is needed.
- How can the two isomers having molecular formula C2H6O be distinguishedby IR spectroscopy?1. COMPOUND CSH100 (pent-2-en-1-ol) A) PREDICT THE UV-VIS SPECTRUM OF THIS COMPOUND AND EXPLAIN. B) CALCULATE THE CHSNO COMPOUND Element Calculated (%) Carbon 69.72 Hydrogen Nitrogen Охудеn Total (%) 11.70 0.00 18.58 100help with the following ochem question part a, b, and c regarding the NMR for the compound.... (5S, 7R)-7-bromo-,3,9-diethyl-6,6-dimethylundec-3,8-dien-5-ol
- 1. An aliphatic ketone absorbs at 1,715 cm-1. What is the frequency of this vibration in hertz, which is cycles per second or just per second, reciprocal seconds? 2. What is the energy equivalent of this stretching vibration in kcal/mole? 3. Why does 3,4-diethyl-3-hexene not have a carbon to carbon double bond stretching absorption band? 4. Why does a carbon to oxygen double bond absorption band have a greater intensity than a carbon to carbon double bond absorption band? 5. Using only IR, explain in detail how one could most easily differentiate between oct-1-ene and oct-1-yne if all carbon to carbon bonds are ignored. 6. Using only IR, explain in detail how one could most easily differentiate between butan-1-ol and butanoic acid.A) Phenol Red is a weakly acidic dye which is yellow in the HA form and red in the A form. What concentration of Phenol Red is required to obtain an absorbance of 0.50 at 550 nm at pH 7.8? Note: ε550 of A = 2.5 x 104 M-1 cm-1; ε550 of HA = 0; pKa = 7.8. B) What would the absorbance of the solution in part (a) be if the pH was 8.8?1. Compound M (C5H100) readily decolorizes Br2 in CCI4 and is converted to compound N (C5H120) by H2/Ni. The 'H NMR spectrum for M is shown below. The C NMR spectrum of M has signals at 146.1, 110.8, 71, and 29.4. Deduce the structures of M 13 and N. Conmoud M Chaacal Sh