Q4: 1. Calculate the enthalpy and entropy of activation (AH and AS*) at 40 °C for the acetolysis of m-chlorobenzyl p-toluenesulfonate from the data given: 2. Determine the value of p for the reaction shown from the data given: + OH™ SO3 OH Temp 25 40 50.1 58.8 Y H CH₂O CH₂ Br NO₂ kx 105 (s ¹) 0.0136 0.085 0.272 0.726 k (M¹s¹) 37.4 21.3 24.0 95.1 1430

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Q4:
1. Calculate the enthalpy and entropy of activation (AH and AS¹) at 40 °C
for the acetolysis of m-chlorobenzyl p-toluenesulfonate from the data
given:
2. Determine the value of p for the reaction shown from the data given:
+ OH™
SO3
OH
Temp
25
40
50.1
58.8
Y
H
CH₂O
CH3
Br
NO₂
kx 105 (s ¹)
0.0136
0.085
0.272
0.726
k (M¹s¹)
37.4
21.3
24.0
95.1
1430
Transcribed Image Text:Q4: 1. Calculate the enthalpy and entropy of activation (AH and AS¹) at 40 °C for the acetolysis of m-chlorobenzyl p-toluenesulfonate from the data given: 2. Determine the value of p for the reaction shown from the data given: + OH™ SO3 OH Temp 25 40 50.1 58.8 Y H CH₂O CH3 Br NO₂ kx 105 (s ¹) 0.0136 0.085 0.272 0.726 k (M¹s¹) 37.4 21.3 24.0 95.1 1430
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