Q1. Which of the following alkyl halides form a substitution product in an SN1 reaction that is different from the substitution product formed in an SN2 reaction? a. CH3 Br Jº CH3CHCHCHCH3 CH3 b. CH3 CH3CH₂C-CHCH3 CH3 Br CH₂Br d. CH3 -Br

Q1. Which of the following alkyl halides form a substitution product in an SN1 reaction that is different from the substitution product formed in an SN2 reaction? a. CH3 Br Jº CH3CHCHCHCH3 CH3 b. CH3 CH3CH₂C-CHCH3 CH3 Br CH₂Br d. CH3 -Br

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter8: Haloalkanes, Halogenation, And Radical Reactions

Section: Chapter Questions

Problem 8.28P

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

Q1. Which of the following alkyl halides form a substitution product in an SN1 reaction
that is different from the substitution product formed in an SN2 reaction?
a.
CH3 Br
I I
CH3CHCHCHCH3
CH3
b.
CH3
CH3CH₂C-CHCH3
CH3 Br
C.+
CH₂Br
d.
CH3
-Br

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Step 1: SN1 mechanism

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Step 2: SN2 mechanism

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Step 3: Given alkyl halides

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