ProVide the major prochuct for each following reactuns H more Than one 5 formed, Circk the major Produ ct -> 2. NBS, hy 1- Bra, FeBr3 2. H2504 -503H J.Bra, FeBr3 2. Mgco) 3. CH2O 4. H307 workup
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- What is the missing reactant in step 2 of the following reaction sequence? H* / H20 d-oC,Hs ? (1) LDA (-78°C) THF II CH,0-C-oC,H; CH3- -OCH5 II IV CH;-OC,H; H Select one: A. I В. IV O C. I| D. IIDtermine the Products from the rxn Me. LDA A CH;I B + Lil -70 °C The Products A and B are Ме Me CH3 A= B= А. Me Me Me A= B= В. OCH3 Me. Me. A= B= С. Me Me. Me A= B= D.product? Uod c). Br Pd cat CO2CH3 1. LDA 2. H2C=0 3. Н.О
- What is the intermediate before the final product of the following reactions? ii NaOH H* heat O a. Na Ob. OH OH Od. Na* он e. Of.Paused Complete the following reactions. 1. +H₂O NaBH mild oxidation Complete the following reactions. 1. Base cat. H3CH2C CH₂CH + H3CH2C- C -CH2CH3 2. OCH3 H3C-C -CH2CH3 + H₂O OCH3 3. 4. CH3 NaBH4 H3CH2C C CH2CH3 + CH3CH2OH 5. mild oxidationCH3 CH3 H3C N. H Tetracaine Tetracaine can be synthesized from benzene. The synthesis involves the following steps: 1. Benzene + CH3CI, AICI3 to form product A; 2. A + HNO3, H2SO4 to form product B; 3. B + KMNO4, H2O to form product C; 4. C + SOCI, to form product D; 5. D + HOCH2CH2N(CH3)2 to form product E; 6. E + H2, Pt to form product F; 7. F + CH3CH2CH2CHO to form product G; 8. G + NABH3CN to form Tetracaine. Draw the structures of product A and product G. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Show the order of synthesis by drawing a reaction arrow between A and G, pointing toward the later-synthesized product.
- GUSUIN CI- H. eviaoxe (MCPBA) elugelom ert notageta brs ainepse pnileil elom ert not eg CH3OH catalytic H2SO4Bet er all parts yeements that hae the ing hbreviated etrn urti 000Qurston 18 Consuder the reatons shown. CI (8) t HCI cl + H2 What type of resction in it? Which is the corred product A,B or C? Name the first reactant the second reactont Name the
- 1) quv LDA Endicate the product in bex and indicate whech is the thermady namil or Kinetic produet CampandE 11 qur LDA D 2) H3C. CH3CH20H Kinetic or thermadynumc 31 HyoT Protonutish kinetre or thermobyhamil 31H31. NaNH2: 2. CH;CH,CHO; 3. H*(quenching): 4. H/Pd/BaSO,/pyridine; 5. OsO,/H,O2 H =H он он он он но HO HO он он но но OH EQUESTION 3 Which of the following structures is NOT a contributing resonance structure A that explains the regiochemistry for the monobromination of toluene? CH3 Br2 Intermediate C-H,Br FeBr3