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Science

Chemistry

principle

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter14: Mixtures And Solutions

Section14.3: Factors Affecting Solvation

Problem 40SSC

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describe the principle of titration

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You are given the following acidbase titration data, where each point on the graph represents the pH after adding a given volume of titrant (the substance being added during the titration). a What substance is being titrated, a strong acid, strong base, weak acid, or weak base? b What is the pH at the equivalence point of the tiration? c What indicator might you use to perform this titration? Explain.
When might a pH meter be better than an indicator to determine the end point of an acid-base titration?
Describe how the amount of sodium hydroxide in a mixture can be determined by titration with hydrochloric acid of known molarity.
Explain how to choose the appropriate acid-base indicator for the titration of a weak base with a strong acid.
Consider 1.0 L of an aqueous solution that contains 0.10 M sulfuric acid to which 0.30 mole of barium nitrate is added. Assuming no change in volume of the solution, determine the pH, the concentration of barium ions in the final solution, and the mass of solid formed.
Consider the titration of HF (K a=6.7104) with NaOH. What is the pH when a third of the acid has been neutralized?
Use Le Chátelier's principle to explain what happens to the equilibrium H2O(l)H+(aq)+OH(aq) when a few drops of HCl are added to pure water.
Follow the directions of Question 64. Consider two beakers: Beaker A has a weak acid(K a=1105). Beaker B has HCI. The volume and molarity of each acid in the beakers are the same. Both acids are to be titrated with a 0.1 M solution of NaOH. (a) Before titration starts (at zero time), the pH of the solution in Beaker A is the pH of the solution in Beaker B. (b) At half-neutralization (halfway to the equivalence point), the pH of the solution in Beaker A the pH of the solution in Beaker B. (c) When each solution has reached its equivalence point, the pH of the solution in Beaker A the pH of the solution in Beaker B. (d) At the equivalence point, the volume of NaOH used to titrate HCI in Beaker B the volume of NaOH used to titrate the weak acid in Beaker A.
Another way to treat data from a pH titration is to graph the absolute value of the change in pH per change in milliliters added versus milliliters added (pH/mL versus mL added). Make this graph using your results from Exercise 61. What advantage might this method have over the traditional method for treating titration data?
Describe in words the titration of an acid with a base. Be sure to use the terms equivalence point, indicator, and end point correctly.